Book ChapterDOI
Crown thioether chemistry
Stephen R. Cooper,Simon C. Rawle +1 more
TLDR
In this paper, the synthesis, structural, and coordination chemistry of crown thioethers with both transition and p-block metal ions is reviewed comprehensively through December 1988, focusing on the electronic structures and redox properties induced in metal ions by coordination to crown thiosethers.Abstract:
The synthetic, structural, and coordination chemistry of crown thioethers with both transition and p-block metal ions is reviewed comprehensively through December 1988. Emphasis falls upon the electronic structures and redox properties induced in metal ions by coordination to crown thioethers. Examples include stabilization of mononuclear Rh(II), Pt(III), and low-spin octahedral Co(II). A subsidiary theme concerns the influence of ligand conformation in determining both the binding efficacy and the qualitative coordination chemistry associated with a given crown thioether. The review concludes with a view toward potential future applications of crown thioethers in catalysis, in sequestration or biological delivery of heavy metal ions, and in fundamental studies directed toward rational design of ligands.read more
Citations
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Crown ethers: sensors for ions and molecular scaffolds for materials and biological models.
Journal ArticleDOI
Supramolecular Luminescent Sensors
TL;DR: Specific focus is placed on the development of new macrocycle hosts since 2010, coupled with considerations of the underlying principles of supramolecular chemistry as well as analytes of interest and common luminophores.
Journal ArticleDOI
Crystal Engineering of Multidimensional Copper(I) and Silver(I) Coordination Supermolecules and Polymers with Functions
TL;DR: A review of the latest developments in our groups with regard to construction of functional crystal metal complex supermolecules from self-assembly of copper(I) and silver (I) coordination compounds by intermolecular interactions as well as coordination bonds is given in this paper.
Book
Localized to Itinerant Electronic Transition in Perovskite Oxides
John B. Goodenough,S. L. Cooper +1 more
TL;DR: In this paper, the metal-insulator transition in Perovskite-Related Oxides is studied. But the authors focus on transport properties and local atomic structure of CMR Manganites and Related Oxides.
Journal ArticleDOI
Synthesis and coordination chemistry of unsymmetrical tetraazaporphyrins containing single oxathia- and thiacrown substituents
TL;DR: The oxathia-and thiaether-crowned porphyrazines were found to coordinate Ag(I) and HgCl 2, though all complexes suffered poor solubility and complexes with the latter were unstable in polar media as mentioned in this paper.
References
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Journal ArticleDOI
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
TL;DR: The effective ionic radii of Shannon & Prewitt [Acta Cryst. (1969), B25, 925-945] are revised to include more unusual oxidation states and coordinations as mentioned in this paper.
Book
Advanced Inorganic Chemistry
TL;DR: Cotton and Wilkinson's Advanced Inorganic Chemistry (AIC) as discussed by the authors is one of the most widely used inorganic chemistry books and has been used for more than a quarter century.
Journal ArticleDOI
X-ray crystal structure analysis of plastocyanin at 2.7 Å resolution
Peter M. Colman,Hans C. Freeman,J.M. Guss,Mitsuo Murata,V. A. Norris,John A. M. Ramshaw,John A. M. Ramshaw,M. P. Venkatappa,M. P. Venkatappa +8 more
TL;DR: The three-dimensional structure of plastocyanin, a blue or "Type 1" copper-protein, has been determined at a resolution of 2.7 A as discussed by the authors, and it is coordinated by a cysteine thiol group, a methionine thioether group and two histidine imidazole groups.
Journal ArticleDOI
The Synthesis and Ion Bindings of Synthetic Multidentate Macrocyclic Compounds.
Book
Experimental Electrochemistry for Chemists
TL;DR: In this article, the authors outline the basic principles and modern methodology of electrochemistry, in such a way that the uninitiated may gain sufficient background to use electrochemical methods for the study of chemical systems.