Journal ArticleDOI
Decomposition pathways of C1C4 alcohols adsorbed on platinum (111)
TLDR
In this paper, the adsorption and decomposition of methanol, ethanol, propan-1-ol and butan-2-ol was studied on clean, and oxygen pre-covered Pt(111) surfaces.About:
This article is published in Surface Science.The article was published on 1982-09-01. It has received 200 citations till now. The article focuses on the topics: Monolayer & Methanol.read more
Citations
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Journal ArticleDOI
In situ infrared spectroscopy at electrochemical interfaces
T Iwasita,F.C Nart +1 more
TL;DR: In this paper, an insight into the in situ FTIR spectroscopy method as applied in Electrochemistry is given, and particular aspects inherent to the electrochemical method are described in a concise form.
Journal ArticleDOI
Oxygenate reaction pathways on transition metal surfaces
Manos Mavrikakis,Mark A. Barteau +1 more
TL;DR: In this article, the decomposition mechanisms of oxygenates on transition metal surfaces focusing primarily on metals of Groups VIII and IB are reviewed and deviations from these serve to illustrate the patterns of oxygenate reactions, and major divisions in the preferred pathways can be rationalized in terms of the affinities of metals for making metaloxygen and metal-hydrogen bonds.
Journal ArticleDOI
DFT studies for cleavage of C$z.sbnd;C and C$z.sbnd;O bonds in surface species derived from ethanol on Pt(111)
TL;DR: In this paper, self-consistent periodic DFT calculations were used to study the relative stabilities and reactivities of surface species on clean Pt(111) slabs derived by subsequent removal of hydrogen atoms from ethanol.
Journal ArticleDOI
Modeling ethanol decomposition on transition metals: a combined application of scaling and Brønsted-Evans-Polanyi relations.
Peter Ferrin,Dante A. Simonetti,Shampa Kandoi,Edward L. Kunkes,James A. Dumesic,Jens K. Nørskov,Manos Mavrikakis +6 more
TL;DR: Experiments on supported catalysts verify that this simple model is reasonably accurate in describing reactivity trends across metals, suggesting that the combination of BEP and scaling relations may substantially reduce the cost of DFT calculations required for identifying reactivity descriptors of more complex reactions.
Journal ArticleDOI
Decarbonylation and decomposition pathways of alcohol's on Pd(111)
J.L. Davis,Mark A. Barteau +1 more
TL;DR: In this paper, the reactions of methanol, ethanol, 1-propanol, and 2-Propanol were examined on the clean Pd(111) surface using temperature programmed desorption (TPD).
References
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Book
CRC Handbook of Chemistry and Physics
TL;DR: CRC handbook of chemistry and physics, CRC Handbook of Chemistry and Physics, CRC handbook as discussed by the authors, CRC Handbook for Chemistry and Physiology, CRC Handbook for Physics,
Journal ArticleDOI
Thermal desorption of gases
TL;DR: In this paper, the activation energy, rate constant and order of reaction from flash-filament desorption experiments were examined, and two heating schedules were considered: a linear variation of sample temperature with time (T = T 0+st), and a reciprocal temperature variation (1 T = 1 T 0 −αt).
Journal ArticleDOI
Oxygen interactions with the Pt(111) surface
TL;DR: Oxygen interaction with the Pt(111) surface has been studied by low energy electron loss (EELS), ultraviolet photoemission (UPS) and thermal desorption (TDS) spectroscopies over the temperature range 100 to 1400 K as mentioned in this paper.
Journal ArticleDOI
The selective oxidation of CH3OH to H2CO on a copper(110) catalyst
Israel E. Wachs,Robert J. Madix +1 more
TL;DR: In this article, the authors studied the oxidation of methanol to formaldehyde by flash decomposition spectroscopy on a single crystal of a Cu(110) single crystal.
Journal ArticleDOI
The interaction of water with the Pt(111) surface
Galen B. Fisher,John L. Gland +1 more
TL;DR: The interaction of water with a platinum surface has been examined by thermal desorption, ultraviolet photoemission, and X-ray photo-emission spectroscopies.
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Decarbonylation and decomposition pathways of alcohol's on Pd(111)
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