Journal ArticleDOI
Density functional study of intermediates in the nickel-catalyzed homo-diels-alder reaction of norbornadiene with alkenes
M. M. Gugelchuk,James A. Wisner +1 more
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This article is published in Organometallics.The article was published on 1995-04-01. It has received 8 citations till now. The article focuses on the topics: Norbornadiene & Diels–Alder reaction.read more
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Transition Metal-Mediated Cycloaddition Reactions
TL;DR: The phytochemical remains of the seven-membered ring formation are still under investigation, but it is clear that the polymethine content of the ring is lower than previously thought, suggesting that it is more likely to be a mixture of 22π and 32σ.
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Recent Advances in Lewis Acid Catalyzed Diels−Alder Reactions in Aqueous Media
TL;DR: In this paper, a review illustrates recent significant results in this field when the Diels−Alder cycloaddition is performed in aqueous medium, showing that it is greatly enhanced by Lewis acid catalysis.
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Transition Metal-Catalyzed [4 + 2 + 2] Cycloadditions of Bicyclo[2.2.1]hepta-2,5-dienes (Norbornadienes) and Bicyclo[2.2.2]octa-2,5-dienes1
TL;DR: The transition-metal-catalyzed [4 + 2 + 2] cycloadditions of norbornadienes, bicyclo[2.2]octa-2,5-diene, and benzobarrelene with 1,3-butadienis proceed in excellent yields using cobalt-based catalytic systems.
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Density Functional Theory Studies of Ruthenium-Catalyzed Bis-Diels−Alder Cycloaddition of 1,5-Cyclooctadiene with Alkynes
Xin Huang,Zhenyang Lin +1 more
TL;DR: In this paper, density functional theory calculations at the B3lyP level have been performed to study the reaction mechanism of the Ru-catalyzed cycloaddition of 1,5-cyclooctadiene (COD) with alkynes.
Journal ArticleDOI
Kinetic and Modeling Studies on the Nickel-Catalyzed Homo-Diels−Alder Addition of 7-Substituted Norbornadienes
TL;DR: Pseudo-first-order rate constants have been determined for several 7-substituted norbornadienes in their nickel-catalyzed homo-Diels−Alder cycloaddition with methyl vinyl ketone as mentioned in this paper.