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Journal ArticleDOI

Density, Refractive Index, and Excess Properties of 1-Butyl-3-methylimidazolium Tetrafluoroborate with Water and Monoethanolamine

TLDR
In this paper, the densities and refractive indices of binary mixtures containing 1-butyl-3-methylimidazolium tetrafluoroborate with water and monoethanolamine are measured at a temperature range of (293.15 to 353.15) K and within the whole range of composition.
Abstract
The densities and refractive indices of binary mixtures containing 1-butyl-3-methylimidazolium tetrafluoroborate with water and monoethanolamine are measured at a temperature range of (293.15 to 353.15) K and within the whole range of composition. Excess molar volumes are deduced from the measured physical properties and correlated using Redlich–Kister polynomial equations. The excess molar volumes are positive for the entire mole fraction range, and the details are discussed. The thermal expansion coefficients are also derived from the measured density values.

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Systematic study of the thermophysical properties of imidazolium-based ionic liquids with cyano-functionalized anions.

TL;DR: A detailed and comprehensive investigation of the influence of the -CN group through an analysis of the thermophysical properties of the related ILs shows that, regardless of the cation, the densities decrease with an increase in the number of cyano groups or anion molecular weight.
Journal ArticleDOI

"Solvent-in-salt" systems for design of new materials in chemistry, biology and energy research.

TL;DR: Inorganic and organic "solvent-in-salt" (SIS) systems have been known for decades but have attracted significant attention only recently and demonstrate remarkable thermal stability and tunability, and present a class of admittedly safer electrolytes, in comparison with traditional organic solvents.
Journal ArticleDOI

Volumetric properties, viscosities and refractive indices of binary liquid mixtures of tetrafluoroborate-based ionic liquids with methanol at several temperatures

TL;DR: In this article, the authors measured the viscosities and refractive indices of two binary systems 1-butyl-3-methylimidazolium tetrafluoroborate [bmim][BF4]+methanol, as well as of all pure components, covering the whole range of compositions at T = (278.15 to 318.15) K and p = 101kPa.
Journal ArticleDOI

Dielectric Relaxation and Solvation Dynamics in a Prototypical Ionic Liquid + Dipolar Protic Liquid Mixture: 1-Butyl-3-Methylimidazolium Tetrafluoroborate + Water

TL;DR: Dielectric and solvation data on mixtures of 1-butyl-3-methylimidazilium tetrafluoroborate + water are reported and used to examine the utility of dielectric solvation models.
Journal ArticleDOI

Thermophysical properties for the mixed solvents of N-methyl-2-pyrrolidone with some of the imidazolium-based ionic liquids

TL;DR: In this article, the thermophysical properties and structure of N-methyl-2-pyrrolidone (NMP) in the binary mixtures with 1-alkyl-3-methyl imidazolium cation [amim]+ with different anions (chloride, methyl sulfate and tetrafluoroborate) of ionic liquids (ILs).
References
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Journal ArticleDOI

Catalysis in ionic liquids

TL;DR: Hydrogenation of Alkenes and Arenes by Nanoparticles 2624 3.1.2.
Journal ArticleDOI

Properties of ionic liquid solvents for catalysis

TL;DR: In this article, a roadmap for the literature values of density, viscosity, melting and glass transition temperatures, thermal stability, empirical solvent parameters, absorption, toxicity, surface tension, heat capacity, and thermal conductivity is provided.
Journal ArticleDOI

Protic Ionic Liquids: Preparation, Characterization, and Proton Free Energy Level Representation †

TL;DR: A perspective on the relations between inorganic and organic cation ionic liquids (ILs), including members with melting points that overlap around the borderline 100 degrees C, and a basis for assessing their relation to aprotic ILs by means of a Gurney-type proton-transfer free energy level diagram.
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