Journal ArticleDOI
Design, synthesis, characterization and electrocatalytic behaviour of a dinuclear palladium(I) complex supported by 1-[(2-chloro)benzene]-3-[(2-carboxmethyl)benzene]triazenide ions
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TLDR
In the presence of HCl, the reaction of 2-chloroaniline, methyl anthranilate and sodium nitrite formed 1-[(2-chloro)benzene]-3-[( 2-carboxymethyl) benzene]triazene (HL) as mentioned in this paper.About:
This article is published in Polyhedron.The article was published on 2019-05-01. It has received 3 citations till now. The article focuses on the topics: Palladium & Triazene.read more
Citations
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The anticancer activity of an air-stable Pd(I)-NHC (NHC = N-heterocyclic carbene) dimer.
Thomas Scattolin,Enrica Bortolamiol,Stefano Palazzolo,Isabella Caligiuri,Tiziana Perin,Vincenzo Canzonieri,Nicola Demitri,Flavio Rizzolio,Luigi Cavallo,Busra Dereli,Manoj V. Mane,Steven P. Nolan,Fabiano Visentin +12 more
TL;DR: A new dinuclear Pd(i) complex coordinating two bis(NHC) ligands revealed an unsuspected stability despite the unsaturation of the two metal centres, and showed high and selective antiproliferative activity against different cancer cell lines and ovarian cancer tumoroids.
Journal ArticleDOI
Synthesis, characterization, magnetic anisotropy and catalytic behaviors of a cobalt complex of S,S′-bis(2-pyridylmethyl)-1,2-thiobenzene
TL;DR: In this article, the magnetic anisotropy of CoBr2 is revealed via the analyses of the direct-current magnetic data with a zero-field splitting (ZFS) parameter (D) of 69.88 cm−1.
References
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Journal ArticleDOI
Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.
R. S. Nicholson,Irving. Shain +1 more
TL;DR: In this paper, the integral equations obtained from the boundary value problems were solved and extensive data were calculated which permit construction of stationary electrode polarograms from theory, making it possible to develop diagnostic criteria so that unknown systems can be characterized by studying the variation of peak current, half-peak potential, or ratio of anodic to cathodic peak currents as a function of rate of voltage scan.
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Multimetallic catalysis based on heterometallic complexes and clusters.
Journal ArticleDOI
Iron-only hydrogenase mimics. Thermodynamic aspects of the use of electrochemistry to evaluate catalytic efficiency for hydrogen generation.
TL;DR: It is demonstrated that direct reduction can be almost completely suppressed by using a mercury or amalgamated gold electrode, even at very negative potentials.
Journal ArticleDOI
Super Atomic Clusters: Design Rules and Potential for Building Blocks of Materials
Puru Jena,Qiang Sun +1 more
TL;DR: This Review describes how different electron-counting rules can lead to the design of stable clusters, mimicking the chemistry of atoms, and highlights the potential of these "superatoms" as building blocks of cluster-assembled materials.
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