Open Access
SADABS, Program for Empirical Absorption Correction of Area Detector Data
About:
The article was published on 1996-01-01 and is currently open access. It has received 3515 citations till now. The article focuses on the topics: Absorption (electromagnetic radiation).read more
Citations
More filters
Journal ArticleDOI
Tunable Rare-Earth fcu-MOFs: A Platform for Systematic Enhancement of CO2 Adsorption Energetics and Uptake
Dong-Xu Xue,Amy J. Cairns,Youssef Belmabkhout,Lukasz Wojtas,Yunling Liu,Mohamed H. Alkordi,Mohamed Eddaoudi +6 more
TL;DR: The study supports the importance of the synergistic effect of exposed open metal sites and proximal highly localized charge density toward materials with enhanced CO2 sorption energetics.
Journal ArticleDOI
Selective gas adsorption and unique structural topology of a highly stable guest-free zeolite-type MOF material with N-rich chiral open channels.
TL;DR: A new multifunctional di-topic tetrazolate-based ligand, 2,3-di-1H-tetrazol-5-ylpyrazine (H(2)dtp) has been designed and synthesized and presents a unique uniform etd (8,3) topology, is the first example of its type in MOFs, and exhibits high thermal stability with the decomposition temperature above 380 degrees C and permanent porosity.
Journal ArticleDOI
Two-Coordinate Co(II) Imido Complexes as Outstanding Single-Molecule Magnets
Xiao-Nan Yao,Jingzhen Du,Yi-Quan Zhang,Xuebing Leng,Mu-Wen Yang,Shang-Da Jiang,Zhenxing Wang,Zhongwen Ouyang,Liang Deng,Bing-Wu Wang,Song Gao +10 more
TL;DR: It is reported that two-coordinate cobalt imido complexes featuring highly covalent Co═N cores exhibit slow relaxation of magnetization under zero direct-current field with a high effective relaxation barrier up to 413 cm-1, a new record for transition metal based SMMs.
Journal ArticleDOI
A new type of N-heterocyclic silylene with ambivalent reactivity.
TL;DR: The synthesis of a novel divalent silicon compound by debromination of the corresponding dibromosilyl precursor is reported, and addition of Me3SiX to the silylene furnishes the corresponding 1,4-adduct which subsequently rearranges to the thermodynamically favored 1,1- adduct.
Journal ArticleDOI
Hydrogenation of carboxylic acids with a homogeneous cobalt catalyst
TL;DR: The homogeneously catalyzed hydrogenation of carboxylic acids to alcohols using earth-abundant cobalt is reported, which pairs Co(BF4)2·6H2O with a tridentate phosphine ligand and reaches turnover numbers of up to 8000.