Journal ArticleDOI
Développement du domaine d'application de la calorimétrie à conduction et de l'analyse calorimétrique différentielle en thermodynamique et en cinétique
J.P. Dubes,M. Barres,H. Tachoire +2 more
Reads0
Chats0
TLDR
In this article, the authors reported first results concerning the simultaneous determination of equilibrium constants and enthalpies of reaction by titration conduction microcalorimetry, and described an electronic on-line corrector.About:
This article is published in Thermochimica Acta.The article was published on 1977-04-01. It has received 20 citations till now.read more
Citations
More filters
Journal ArticleDOI
Thermokinetic method for faster enzyme-catalyzed reactions
TL;DR: In this article, a double-parameter theoretical model of the conduction calorimeter was proposed to determine the thermokinetics of short-time enzymatic reactions, which can be used to calculate both molar reaction enthalpy ( Δ r H m ) and kinetic parameters ( K m, ν max ) of these reactions.
Journal ArticleDOI
An experimental verification and comparison of the use of passive and active thermal-electronic networks in dynamic calorimetric measurements
TL;DR: The experimental verification has been realized according to recommendations elaborated for comparing dynamic calorimetric methods and a feedback compensation method, improved by a transfer function corrector, works on the basis of a combination of an active and passive thermal-electronic network.
Journal ArticleDOI
Calorimetric models: Theory and application
TL;DR: In this paper, the authors present the basis of the determination of mathematical models of calorimetic systems and the applications of these models for the elaboration of a classification of Calorimetric systems; the analysis of the course of heat effects in calorimeters; and analysis of dynamic properties, including total heat effects and thermokinetics.
Journal ArticleDOI
Quality and limits of a thermokinetic method to study gas—solid interactions
TL;DR: In this article, the adsorption of separate doses of oxygen on an initially nearly stoichiometric nickel oxide was studied at 473 K by two independent methods: calorimetry and pressure measurements.
References
More filters
Journal ArticleDOI
Sur l’obtention des courbes de thermogenèse à partir des courbes enregistrées au microcalorimètre de E. Calvet
E. Calvet,F. Camia +1 more
Journal ArticleDOI
Application à l'adsorption et à la catalyse hétérogène d'une méthode de recherche de la thermocinétique exacte
TL;DR: In this paper, a methode de correction is proposed for correction des courbes calorimetriques deformees par l'inertie thermique du calormetre and, donc, for determination des thermo- cinetiques.
Journal ArticleDOI
Détermination des constantes thermodynamiques d'équilibres en solution par calorimétrie à conduction et flux de réactif: I. Description de la méthode
TL;DR: In this article, an injection apparatus attached to the two elements of a conduction microcalorimeter allows measurement of the thermal change arising from displacement of the equilibria in the liquid phase.
Journal ArticleDOI
Application à l’adsorption et à la catalyse hétérogène d’une méthode de recherche de la thermocinétique exacte: II. — Vérification de la validité du modèle et détermination pratique des programmes de correction
Journal ArticleDOI
Détermination du modèle thermocinétique d'un phénomène par convolution avec la fonction d'appareil optimisation des paramètres de ce modèle
R. Romanetti,C. Zahra +1 more
TL;DR: In this paper, a method is presented which calculates the thermogram by optimizing the parameters of a theoretical model, which introduces the characteristics of the apparatus by a convolution technique, and it is unnecessary to assume an analytical form of this function as in previous methods of analysis by deconvolution.