Journal ArticleDOI
Diamminbis(1,5‐cyclooctadien)(μ‐1,4,10,13‐tetraoxa‐7,16‐diazacyclooctadecan‐N7,N16)dirhodium‐bis (hexafluorophosphat): Ein Makrocyclus als Ligand der ersten und zugleich der zweiten Koordinationssphäre
Howard M. Colquhoun,Simon M. Doughty,Alexandra M. Z. Slawin,J. Fraser Stoddart,David J. Williams +4 more
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This article is published in Angewandte Chemie.The article was published on 1985-02-01. It has received 7 citations till now.read more
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Cyclodextrins as Second Sphere Ligands for Transition Metal Complexes—The X-Ray Crystal Structure of [Rh(cod)(NH3)2·α-cyclodextrin][PF6]·6H2O†
Journal ArticleDOI
Second-Sphere Coordination
TL;DR: In this paper, the second-sphere adducts with transition metal complexes have been used to synthesize synthetic receptors, able to recognize and bind transition metal compounds. But the effect of second-space coordination on the chemical, electrochemical, and photochemical properties of the adduct, as well as on their geometries in solution and in the solid state, has been investigated.
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Koordination in zweiter Sphäre — eine neuartige Rolle für Rezeptormoleküle
TL;DR: In this paper, aufgebot an nicht-kovalenten Bindungen-einschlieslich elektrostatischer Krafte, Wasserstoffbruckenbindungen, Charge-Transfer-and van-der-Waals-Wechselwirkungen is presented.
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Cyclodextrine als Liganden zur Koordination von Übergangsmetallkomplexen in der zweiten Sphäre; Röntgen-Strukturanalyse von [Rh(cod) (NH3)2·α-cyclodextrin] [PF6]·6 H2O†
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Simultane primäre und sekundäre Koordination eines neutralen Liganden in einem makrocyclischen Rhodium(III)‐Komplex
TL;DR: In this article, a macrocycle de soufre et oxygene, H 2 O est liee primairement a Rh(III) et secondairement par 2 liaisons stabilisantes aux atomes O du coordinat.
References
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Cryptates—XI: Complexes macrobicycliques, formation, structure, proprietes
TL;DR: In this paper, the macrobicyclic compounds 1−7 form inclusion complexes with alkali and alkaline-earth metal cations, termed cryptates, the metal cation is contained in the intramolecular cavity of the bicyclic system.
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Copper(II) chemistry in hexaaza binucleating macrocycles: hydroxide and acetate derivatives
TL;DR: In this paper, the authors discuss the properties and properties of magnetiques of complexes of [Cu 2 (OH) (ClO 4 )⊂A] (Cl O 4 ) 2 •CHCl 3 et [Cu OAc) 2 A](ClO4 ) 2, avec A=hexaaza-1,4,7,13,16,19,19 dioxa-10,22 cyclotetracosane
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