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Journal ArticleDOI

Diesel Soot Oxidation with NO2: Engine Experiments and Simulations

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TLDR
In this article, the effect of NO2 as an active oxidation agent in the regeneration process of the soot accumulated in the particulate filter was investigated at realistic conditions using a diesel engine equipped with a standard oxidation catalyst and a particle filter.
Abstract
The diesel particulate filters (DPFs) technology has impressively advanced especially during the last years, driven by the interest in the reduction of automobile particulate emissions. This paper is concerned with the effect of NO2 as an active oxidation agent in the regeneration process of the soot accumulated in the particulate filter. Experiments at realistic conditions using a diesel engine equipped with a standard oxidation catalyst and a particulate filter are carried out at a wide range of operating conditions. These results are used to validate an already available mathematical model of the NO2-assisted regeneration phenomena in the particulate filter. The combined use of experimental and modeling results provides interesting conclusions regarding the significance and the chemistry of the reaction of soot with NO2. The advantages and drawbacks of such an approach compared to standard laboratory synthetic gas studies are discussed. The agreement between experimental and simulation results in terms...

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Citations
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Journal ArticleDOI

Comprehensive kinetic characterization of the oxidation and gasification of model and real diesel soot by nitrogen oxides and oxygen under engine exhaust conditions: Measurement, Langmuir–Hinshelwood, and Arrhenius parameters

TL;DR: In this article, the reaction kinetics of the oxidation and gasification of four types of model and real diesel soot (light and heavy duty vehicle engine soot, graphite spark discharge soot and hexabenzocoronene) by nitrogen oxides and oxygen have been characterized for a wide range of conditions relevant for modern diesel engine exhaust and continuously regenerating particle trapping or filter systems.
Journal ArticleDOI

Oxidation of carbon by NOx, with particular reference to NO2 and N2O

TL;DR: In this paper, the authors found that two types of active sites were present; one forming weak bonds (physisorption), and the other undergoing chemisorption to form groupings such as -C-ONO, -C -ONO2 or -C −NO2.
Journal ArticleDOI

One-dimensional automotive catalyst modeling

TL;DR: In this article, the bulk gas equations of automotive catalysts are reformulated based on the governing equations of inviscid flow, while retaining full transient capability, which can be used to calibrate the simpler models by determining the actual residence time within the catalyst.
Journal ArticleDOI

Modelling of soot oxidation by NO2 in various types of diesel particulate filters

TL;DR: In this article, a 2D nonstationary model of the filter, soot filtration and regeneration with detailed kinetics of soot combustion, and spatially 1D plug-flow model of DOC are presented and utilized to compare various catalytic systems for soot oxidation by NO 2 and O 2.
Journal ArticleDOI

Interaction mechanism of NO2 with carbon black: effect of surface oxygen complexes

TL;DR: In this paper, a desorption process has been proposed to identify the adsorbed species by measuring the amounts of evolved gases NO, NO2, CO and CO2.
References
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Journal ArticleDOI

The oxidation of soot: a review of experiments, mechanisms and models

TL;DR: In this paper, the experimental techniques which have been used to study the gasification of soot are described and the methods and results obtained by analysis of the data from them are considered.
Journal ArticleDOI

Kinetics of the oxidation of carbon black by NO2: Influence of the presence of water and oxygen

TL;DR: In this article, a parametric study of the effects of the temperature, NO 2, O 2 and H 2 O concentrations was performed, with a one-dimensional model of NO 2 consumption along the thickness of the carbon black bed, and a phenomenological law was proposed, accounting for the effect of the presence of oxygen and water.
Journal ArticleDOI

Thermal regeneration of diesel-particulate monolithic filters

TL;DR: In this paper, a mathematical model is developed to describe the process of thermal regeneration in diesel-particulate monolithic filters, and the model shows that a typical regeneration cycle consists of four stages: preheating, ignition, transport-controlled combustion, and cooling.
Journal ArticleDOI

Modes of Catalytic Regeneration in Diesel Particulate Filters

TL;DR: In this article, a 1D mathematical model of the catalytic regeneration in the channel of the particulate filter is based on a dynamic oxygen storage/release mechanism of additive action coupled to the transport phenomena occurring in the filter.
Journal ArticleDOI

The influence of NOx on soot oxidation rate: molten salt versus platinum

TL;DR: In this article, a systematic study was carried out to assess the influence of simulated diesel exhaust on the activity of molten salt, Cs2SO4·V2O5, supported on ceramic foam and Pt/-alumina catalysts in the oxidation of diesel soot.
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