Journal ArticleDOI
Differential Capacity of Mercury in Aqueous Sodium Fluoride Solutions. I. Effect of Concentration at 25
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This article is published in Journal of the American Chemical Society.The article was published on 1954-10-01. It has received 277 citations till now. The article focuses on the topics: Mercury (element) & Sodium fluoride.read more
Citations
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Work function, electronegativity, and electrochemical behaviour of metals
TL;DR: In this article, it was shown that the best relationship between the two above quantities is expressed by the equations: E z =−4.61 −0.40 α, where α=(2.10−x M )/0.6 is defined as the degree of orientation of water at the interface.
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Molecular Insights into the Potential and Temperature Dependences of the Differential Capacitance of a Room-Temperature Ionic Liquid at Graphite Electrodes
TL;DR: An observed decreased DC and the disappearance of the minimum in DC near the PZC with increasing temperature are likely due to the increasing importance of entropic/excluded volume effects (interfacial crowding) with increasingTemperature.
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Electrosorption of ions from aqueous solutions by carbon aerogel: An electrical double-layer model
TL;DR: In this article, an electrical double-layer model is developed to predict electrosorption of ions from aqueous solutions by carbon aerogel electrodes, and the model focuses on the electros...
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Adsorption at the rutile-solution interface: i. thermodynamic and experimental study.
Y.G. Bérubé,P.L. De Bruyn +1 more
TL;DR: In this paper, a detailed thermodynamic analysis of the double layer at the interface, simple inorganic oxide-aqueous solution, is presented with special emphasis on the assumptions normally made in relating experimental observation to theoretical treatment.
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Structure et propriétés de la couche double électrochimique à l'interphase argent/solutions aqueuses de fluorure de sodium
TL;DR: The role of the cristalline superficielle d'electrodes planes d'argent dans leur comportement electrochimique is investigated in this article.
References
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Journal ArticleDOI
The Free Energy of Hydration of Gaseous Ions, and the Absolute Potential of the Normal Calomel Electrode
TL;DR: In this article, the free energies of hydration of the alkali and halide ions are found to agree reasonably well with the simple expression of Born (ΔF=(1−1/D)Ne2/2re) for solution of charged spheres in a dielectric medium, provided the crystal radii are suitably modified so as to correspond to the radii of the cavities in the dielectrics.
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Effects of Dielectric Saturation upon the Diffuse Double Layer and the Free Energy of Hydration of Ions
TL;DR: The theory of the diffuse double layer was developed for the case of variable dielectric constant in this article, where the authors derived the Born equation for the free energy of hydration of ions.
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The Rate Constant of Ethane Formation from Methyl Radicals
Robert Gomer,G. B. Kistiakowsky +1 more
TL;DR: In this article, the rotating sector technique has been applied to a determination of the rate constant of methyl radical recombination in the photo-decompositions of acetone and mercury dimethyl, using the small but accurately measurable rate of methane formation as a measure of methyl steadystate concentration.
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Free Radicals by Mass Spectrometry. IV. The Rate of Combination of Methyl Radicals
K. U. Ingold,F. P. Lossing +1 more
TL;DR: In this article, the rate of combination of methyl radicals produced by the thermal decomposition of mercury dimethyl has been studied with a free radical mass spectrometer over a large range of temperature (161° to 814°C) and at one temperature (735°C).