Journal ArticleDOI
Effect of 2-Chloro-1,3,2-dioxaphospholane on the radical polymerisation of acrylonitrile, styrene and methyl methacrylate
TLDR
In this paper, the effect of 2-Chloro-1,3,2-dioxaphospholane on the AIBN initiated polymerisation of acrylo was investigated kinetically in benzene at 60 − 80°C.Abstract:
The effect of 2-Chloro-1,3,2-dioxaphospholane on the AIBN initiated polymerisation of acrylo — nitrile , methyl methacrylate and styrene was investigated kinetically in benzene at 60 – 80°C. With acrylonitrile normal kinetic orders with respect to monomer and AIBN could be observed with the phospholane behaving as a chain transfer agent. With methyl methacrylate and styrene it was observed that the phospholane causes enhancement of the rates due to concurrent radical and ionic polymerisation besides functioning as a chain transfer agent.read more
Citations
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Journal ArticleDOI
Anomeric effect and theoretical vibrational spectra compared to the experiment in 2-chloro-1,3,2-dioxaphosphorinane-2-oxide, -sulfide, and -selenide. I. Anomeric effect and structures
W. Förner,H. M. Badawi +1 more
TL;DR: In this paper, a 6-311G basis set was used to study the energy properties of oxides, sulfide, and selenide at the DFT/B3LYP level and several ab initio methods.
Journal ArticleDOI
Anomeric effect, ring inversion, structural stability and vibrational assignments of 2-chloro-1,3,2-dioxaphospholane 2-oxide and 2-sulfide, c-C2H4O2PXCl (X is O or S)
TL;DR: The structural stability and ring inversion of 2-chloro-1,3,2-dioxaphospholane 2-oxide and 2-sulfide were investigated by the DFT-B3LYP and the ab initio MP2 calculations with 6-311+G ∗∗ basis set as discussed by the authors.
Journal ArticleDOI
Theoretical vibrational spectra compared to the experiment and the anomeric effect in 2-chloro-1,3,2-dioxaphosphorinane-2-oxide, -sulfide, and -selenide. II. Vibrational spectra and assignments
H. M. Badawi,W. Förner +1 more
TL;DR: In this article, a 6-311G* basis set of 2-Chloro-1,3,2-dioxaphosphorinane-2-oxide, -sulfide, and -selenide was used for the assignment of symmetry coordinates.
References
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Journal ArticleDOI
Effects of phosphorous oxychloride, phosphorous trichloride and dichlorophenylphosphine on the radical polymerisation of acrylonitrile under heterogeneous conditions
TL;DR: In this paper, the effects of C6H5PCl2, POCl3, and PCl3 on the free radical polymerisation of acrylonitrile initiated bya,a′-azobisisobutyronitrile were kinetically investigated in benzene and trichloroethylene solutions.
Journal ArticleDOI
Cationic polymerization of styrene initiated by phosphorus oxychloride
TL;DR: Cationic polymerization of styrene (St) initiated by phosphorus oxychloride was carried out at 30° in dichloromethane and nitrobenzene as discussed by the authors.