Journal ArticleDOI
Electrochemical study of the transfer of uncouplers across the organic/aqueous interface
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In this article, the potential step chronoamperometry and cyclic voltammetry were interpreted in terms of the facilitated transfer of protons from the water to the nitrobenzene phase by the dissociated form.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1991-02-01. It has received 10 citations till now. The article focuses on the topics: Nitrobenzene & Cyclic voltammetry.read more
Citations
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Journal ArticleDOI
Water-oil partition profiling of ionized drug molecules using cyclic voltammetry and a 96-well microfilter plate system.
TL;DR: The procedure based on 96-well microfilter plates with microporous filters to support 96 organic liquid membranes is shown to be useful for determining logP of ionized drugs in a rapid and efficient way.
Journal ArticleDOI
Indole-based perenosins as highly potent HCl transporters and potential anti-cancer agents
Laura A. Jowett,Ethan N. W. Howe,Vanessa Soto-Cerrato,Wim Van Rossom,Ricardo Pérez-Tomás,Philip A. Gale +5 more
TL;DR: A new library of indole-based perenosins and their anion transport properties is reported, which demonstrated superior transmembrane transport efficiency when compared to other indoles-based transporters, due to favourable encapsulating effects from the substituents on the perenOSin backbone.
Journal ArticleDOI
Transfer Mechanism of Ionic Drugs: Piroxicam as an agent facilitating proton transfer
Frédéric Reymond,Guillaume Steyaert,Alessandra Pagliara,Pierre-Alain Carrupt,Bernard Testa,H. Hubert Girault +5 more
TL;DR: In this paper, it was shown that the NSAID piroxicam and its derivatives act as ionophores for proton transfer across the H2O/1,2-dichloroethane interface.
Journal ArticleDOI
The pH-partition profile of the anti-ischemic drug trimetazidine may explain its reduction of intracellular acidosis.
Frédéric Reymond,Guillaume Steyaert,Pierre-Alain Carrupt,Didier Morin,Jean-Paul Tillement,Hubert H. Girault,Bernard Testa +6 more
TL;DR: This behavior suggests a physiochemical mechanism whereby efflux of protonated TMZ out of an acidified cell is facilitated, in effect exporting protons to extracellular space.
Reference EntryDOI
Liquid/Liquid Interfaces, Electrochemistry at
TL;DR: In this paper, the thermodynamics in biphasic systems are presented in order to show how ions are distributed between the two adjacent phases and hence, how a Galvani potential difference is established at an ITIES.
References
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Journal ArticleDOI
Electrochemical polarization phenomena at the interface of two immiscible electrolyte solutions
TL;DR: The faradaic and non-faradaic processes taking place at the interface of two immiscible electrolyte solutions have been compared with analogous processes occurring at interface metal-electrolyte solution as discussed by the authors.
Journal ArticleDOI
Uncoupling of oxidative phosphorylation.
TL;DR: The mechanism of oxidative phosphorylation is one of the most important problems in classical biochemistry, which has defied a solution for over thirty years as discussed by the authors, and recent studies of photo-affinity labeling and equilibrium binding by uncouplers have contributed new insights into this problem.
Journal ArticleDOI
Electrochemical polarization phenomena at the interface of two immiscible electrolyte solutions—III. Progress since 1983
TL;DR: In this paper, a review of the literature on ion transfer at the interface of two immiscible electrolyte solutions is presented, with a focus on facilitated ion transfer and electron transfer across ITIES.
Journal ArticleDOI
A.c. polarographic study of ion transfer at the water/nitrobenzene interface
TL;DR: In this paper, the transfer of tetramethylammonium (TMA+) ion across the interface between LiCl aqueous solution and a 0.1 mol dm−3 tetrabutyammonium tetraphenylborate nitrobenzene solution was investigated by means of phase-selective a.c. polarography.
Related Papers (5)
Determination of aniline traces in nitrobenzene by the facilitated proton transfer across the water/nitrobenzene interface
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Thermodynamic aspects of the electron transfer across the interface between water and a hydrophobic redox-active ionic liquid
Jan Langmaier,Zdeněk Samec +1 more