Journal ArticleDOI
Electron-transfer processes: The electrochemical and chemical behavior of nitrosobenzene
TLDR
In this article, the electrochemical and chemical reduction of nitrosobenzene has been studied in acetonitrile and dimethylformamide, and the reduction has been shown to be a kinetically controlled process which initially gives rise to the corresponding radical anion.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1974-12-10. It has received 36 citations till now. The article focuses on the topics: Nitrosobenzene & Hydroxide.read more
Citations
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Photochemical activity of a key donor–acceptor complex can drive stereoselective catalytic α-alkylation of aldehydes
TL;DR: It is shown that easily available chiral organic catalysts can guide both the stereoselectivity-defining events and, through the transient formation of photon-absorbing chiral electron donor–acceptor complexes, the photoactivation of the substrates.
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Electrochemical reduction of nitrobenzene and 4-nitrophenol in the room temperature ionic liquid [C4dmim][N(Tf)2]
TL;DR: In this paper, cyclic voltammetry in the room temperature ionic liquid 1-butyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide [C 4 dmim][N(Tf) 2 ] on a gold microelectrode was used to study the reduction of nitrobenzene and 4-nitrophenol.
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Ultrafast interfacial electron transfer from the excited state of anchored molecules into a semiconductor
TL;DR: In this paper, a femtosecond time-resolved two-photon photoemission (TR-2PPE) signal was used to determine the adsorption geometry of a large organic chromophore perylene with different anchor/bridge groups.
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Homolytic base-promoted aromatic alkylations by alkylmercury halides
TL;DR: In this article, electron transfer chain reactions leading to substitution in electronegatively substituted benzene derivatives can be observed with alkylmercury halides in the presence of proton acceptors such as...
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Electrophilic Pt(II) Complexes: Precision Instruments for the Initiation of Transformations Mediated by the Cation−Olefin Reaction
TL;DR: This Account details the efforts to realize catalyst control over this most fundamental of reactions and thereby access steroid like compounds and is intrigued by the role of neighboring group participation in the cyclase phase.
References
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Polarography in Acetonitrile.1 I. Metal Ions which Have Comparable Polarographic Properties in Acetonitrile and in Water
I. M. Kolthoff,J. F. Coetzee +1 more
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The Electrochemical Reduction of Aromatic Azo Compounds
Joe L. Sadler,Allen J. Bard +1 more
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Generalized Circuits for Electroanalytical Instrumentation.
W. M. Schwarz,Irving. Shain +1 more
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Electrogenerated chemiluminescence. I. Mechanism of anthracene chemiluminescence in N,N-dimethylformamide solution
Larry R. Faulkner,Allen J. Bard +1 more
TL;DR: Chandross, Longworth, and Viscoz as discussed by the authors showed that the emission spectrum comprises two or more components, the spectral distribution of the component shortest in wavelength is similar to that of anthracene fluorescence, but the others are broad, structureless, and located toward the red with respect to the first component.