Electron transfer reactions of ruiii(edta) containing the n-heterocyclic ligand pyrazine: kinetic and mechanistic studies
Debabrata Chatterjee,Rudi van Eldik +1 more
- Vol. 13, Iss: 3, pp 193-200
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The article was published on 2020-01-01 and is currently open access. It has received 6 citations till now. The article focuses on the topics: Electron transfer & Pyrazine.read more
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Electrochemistry of Ru(edta) complexes relevant to small molecule transformations: Catalytic implications and challenges
Debabrata Chatterjee,Debabrata Chatterjee,Maria Oszajca,Anna Katafias,Rudi van Eldik,Rudi van Eldik,Rudi van Eldik +6 more
TL;DR: In this paper, results of the electrochemical studies of both mononuclear and binuclear complexes of Ru(edta) are reviewed with regard to electron-transfer reaction mechanism and activity, highlighting their potential to act as redox mediators or catalysts in electrochemical transformations of small molecules and enzymatic reactions.
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RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism
Debabrata Chatterjee,Debabrata Chatterjee,Marta Chrzanowska,Anna Katafias,Maria Oszajca,Rudi van Eldik,Rudi van Eldik,Rudi van Eldik +7 more
TL;DR: In this paper, the role of the coordinated water molecule (by its absence or presence in the primary coordination sphere) in controlling the mechanistic pathways, outer-sphere or innersphere, is discussed.
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Oxidoreductase mimicking activity of Ru(edta) complexes in conversion of NAD coenzymes
TL;DR: In this paper , the potential of Ru(edta) complexes mimicking oxidoreductase enzymes in the redox conversion of NAD coenzymes has been explored in the present work.
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Application of Ru(edta) complexes in biomimetic activation of small molecules. Kinetic and mechanistic impact
TL;DR: In this article , the authors assess the potential of Ru(edta) complexes as a potential model for rational understanding the role of the metalloenzymes that efficiently catalyze the transformation of small molecules to value added product(s).
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Application of Photo-inactive Ru(edta) complexes in Photocatalytic Small Molecules Transformation over Semiconductor Surface – A Perspective
TL;DR: In this paper , a review of the application of ruthenium(III) complexes comprising "edta" ligand as a "redox mediator" or "relay" in photocatalytic electron transfer reaction pertaining to the conversion of small substrate molecules viz. hydrazine to ammonia, bicarbonate to formate, dioxygen to hydrogen peroxide.
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Chemical kinetics and reaction mechanisms
TL;DR: Reactions and reaction rates reactions with a simple kinetic form reversible and concurrent reactions consecutive reactions - the steady state and other approximations consecutive mechanisms - intermediates and numerical solutions deduction of reaction mechanisms transition state theory and microscopic reversibility chain reactions and oscillating reactions reactions in solution extrakinetic probes of mechanism reactions at extreme rates.