Journal ArticleDOI
Electronic structure and bonding in manganese pentacarbonyl halides and hydride
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This article is published in Inorganic Chemistry.The article was published on 1970-05-01. It has received 85 citations till now. The article focuses on the topics: Hydride & Manganese.read more
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51V-NMR und IR-untersuchungen an [V(CO)5EZ3]− -Komplexen
Dieter Rehder,Joern Schmidt +1 more
TL;DR: In this article, anordnung der Liganden EZ 3 nach einer summarischen Liganderstarke untersucht was untertucht, auf der basis of 51 V-NMRsowie IR-Spektren.
Journal ArticleDOI
Octahedral metal carbonyls—XXIII Metal-carbon stretching spectra for disubstituted derivatives of the group VI-B metal carbonyls☆
TL;DR: In this paper, the i.r. spectra in solution in the region 700-300 cm−1 for 26 complexes of the type cis-(bidentate)M(CO)4 (bidentates = bidentate chelating ligand bonding through N, P, As or S donor atoms; M = Cr, Mo, W) have been obtained.
Journal ArticleDOI
Preparation and Characterization of Ethylenediaminetrihalogenonitrosylruthenium(III) Complexes
Hiroshi Tomizawa,Kazumasa Harada,Eiichi Miki,Kunihiko Mizumachi,Tatsujiro Ishimori,Akio Urushiyama,Masayoshi Nakahara +6 more
TL;DR: A mixture of mer-and fac-[RuCl3(en)NO], and mer-[RuX3(n)NO] (X = Cl, Br, or I) were prepared from the corresponding [RuX5NO]2− or hydrous RuX3·NO (X= Cl or Br) and en·2HX (en = ethylenediamine; X = Cl or BR) as discussed by the authors.
Journal ArticleDOI
V-51 and Mn-55 NMR Studies of Metal Carbonyls
TL;DR: In this article, the metal chemical NMR shifts of metal carbonyls are reported and discussed in relation to the bonding nature characteristic of carbonyl compounds of the M(CO)6- and Mn( CO)5X-types, where M is V or Mn, and X is a halogen or SCN.
Journal ArticleDOI
Reactions of transition metal carbonyls with nucleophilic reagents: reactivity and bonding☆
TL;DR: In this paper, an initial investigation into the reactions of organomagnesium halide reagents with metal carbonyls indicate this reaction to be adaptable to relative rate studies of nucleophilic attack on the carbonyl carbon.
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F. A. Cotton,C. S. Kraihanzel +1 more