Journal ArticleDOI
Electronic structure and bonding in manganese pentacarbonyl halides and hydride
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This article is published in Inorganic Chemistry.The article was published on 1970-05-01. It has received 85 citations till now. The article focuses on the topics: Hydride & Manganese.read more
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Approximate molecular orbital calculations on carbene ligands and complexes: the ability of the carbene ligands to act as σ donors and π acceptors
Toby F. Block,Richard F. Fenske +1 more
TL;DR: In this article, nonparameterized molecular orbital calculations have been performed on a series of carbene ligands, C(X)Y, and carbene complexes, (CO)5CrC( X)Y.
Journal ArticleDOI
An improved synthetic method and vibrational study of (pentamethylcyclopentadienyl) dicarbonylrhenium dihalides (η5-C5Me5)Re(CO)2X2 (X = C1, Br and I)
TL;DR: In this paper, an improved synthetic method has been found for the preparation of the pentamethylcyclopentadienyl rhenium dicarbonyldihalide complexes.
Journal ArticleDOI
Variable-energy photoelectron spectroscopy of substituted rhenium and manganese pentacarbonyls: molecular orbital assignments and the interatomic resonant effect.
TL;DR: The results provide firm molecular orbital assignments for all of these molecules and a new resonant effect on the ligand-based orbitals is shown to be mainly due to the interatomic resonanteffect.
Journal ArticleDOI
A solid-state 55Mn NMR spectroscopy and DFT investigation of manganese pentacarbonyl compounds.
TL;DR: The variety of distinct powder sample lineshapes obtained demonstrates the sensitivity of solid-state (55)Mn NMR to the local bonding environment, including the presence of crystallographically unique Mn sites, and facilitates the extraction of the Mn chemical shift anisotropies, CSAs, and the nuclear quadrupolar parameters.
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F. A. Cotton,C. S. Kraihanzel +1 more