Journal ArticleDOI
Electronic structure and bonding in manganese pentacarbonyl halides and hydride
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This article is published in Inorganic Chemistry.The article was published on 1970-05-01. It has received 85 citations till now. The article focuses on the topics: Hydride & Manganese.read more
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Book ChapterDOI
Recent Developments in Theoretical Organometallic Chemistry
TL;DR: In this paper, the authors discuss the general availability of high-speed computers for organic chemistry and discuss the role of bridging groups in metal carbonyl and metallocarborane cluster compounds.
Journal ArticleDOI
Relativistically parameterized extended Hückel calculations. IX: An iterative version with applications to some xenon, thorium and uranium compounds
Sven Larsson,Pekka Pyykkö +1 more
TL;DR: In this paper, a chargeconsistent version of the relativistic extended Huckel method REX is presented and the diagonal matrix elements are corrected for occupations of individual orbitals on the same atom using derivatives from atomic Dirac-Slater calculations and for external charges.
Book ChapterDOI
[16] Resonance Raman studies of ligand binding
TL;DR: The power of resonance Raman spectroscopy for ligand binding studies lies in its ability to detect the metal-ligand vibrations in both model complexes and hemoproteins as discussed by the authors.
Journal ArticleDOI
Oxygen-17 nuclear magnetic resonancé spectra of transition metal carbonyl compounds
TL;DR: In this article, the natural abundance 17 O NMR shielding values observed by FTNMR in the present study on a representative variety of terminal transition metal carbonyl complexes are shown to range 400-300 ppm downfield from 17 OH 2.
Journal ArticleDOI
New diphosphine-substituted carbonyl complexes of manganese
Rolf H. Reimann,Eric Singleton +1 more
TL;DR: In this article, the steric and chelating properties of the diphosphine ligands of Mn 2 (CO) 10 were investigated in terms of steric properties of a dimeric species containing a single diphophosphine bridge and complexes of stoichiometry.
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