Journal ArticleDOI
Electronic Structure and Redox Properties of the Clusters [Ru3O(CH3CO2)6L3]n+
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This article is published in Inorganic Chemistry.The article was published on 1978-01-01. It has received 180 citations till now. The article focuses on the topics: Electronic structure.read more
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Electron Transfer on the Infrared Vibrational Time Scale in the Mixed Valence State of 1,4-Pyrazine- and 4,4‘-Bipyridine-Bridged Ruthenium Cluster Complexes
Tasuku Ito,Tomohiko Hamaguchi,Haruko Nagino,Tadashi Yamaguchi,Hiroaki Kido,Igor S. Zavarine,Todd Richmond,John Washington,Clifford P. Kubiak,Clifford P. Kubiak +9 more
TL;DR: In this article, the intercluster charge transfer complex of the triruthenium clusters is defined and two discrete and reversible single electron reductions are evident by cyclic voltammetry in the redox chemistry of 1−5.
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Monomeric and extended oxo-centered triruthenium clusters
TL;DR: In this paper, the chemistry of μ-oxo-centered trinuclear ruthenium-carboxylate clusters has been dealt with special emphasis on their spectroscopic and electrochemical properties, as well as their capability to form ligand-bridged oligomeric structures exhibiting pronounced electronic delocalization.
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The Versatile Chemistry of 1,4‐Diazines: Organic, Inorganic and Biochemical Aspects
TL;DR: In this paper, 1,4-diazines have been used to study inter-and intramolecular electron transfer in organic, inorganic and biochemical reactions, such as bioluminescent natural products.
Journal ArticleDOI
Electronic interaction in trimeric mixed valence clusters
TL;DR: In this article, double exchange is generalized to mixed valence (MV) trinuclear clusters and the results obtained by quantum-theoretical calculations of exchange and resonance splittings are compared to the results of the model theory which takes account of Heisenberg and double exchange.
Journal ArticleDOI
Oxo-Centered Mixed-Ligand Triruthenium Complexes Having Redox-Active N-Methyl-4,4‘-bipyridinium Ions (mbpy+). Reversible Multistep Electrochemical Properties of [RuIII2RuII(μ3-O)(μ-CH3CO2)6(mbpy+)2(CO)]2+ and [RuIII3(μ3-O)(μ-CH3CO2)6(mbpy+)2(L)]3+ (L = H2O and N-Heterocyclic Ligands)
Masaaki Abe,Yoichi Sasaki,Yasuko Yamada,Keiichi Tsukahara,Shigenobu Yano,Tadashi Yamaguchi,Masato Tominaga,Isao Taniguchi,Tasuku Ito +8 more
TL;DR: In this article, a series of oxo-centered acetate-bridged triruthenium comlexes having two redox-active N-methyl-4,4,bipyridinium ions (mbpy+) have been prepared, and their reversible multistep and multielectron electrochemical properties are reported.