Journal ArticleDOI
.eta.5-Cyclohexadienyltricarbonylchromium(0) complexes from addition of carbon nucleophiles to .eta.6-benzenetricarbonylchromium(0). Formation, chemical and spectroscopic features, and x-ray diffraction analysis
Martin F. Semmelhack,H. T. Hall,R. Farina,M. Yoshifuji,G. Clark,T. Bargar,K. Hirotsu,Jon Clardy +7 more
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This article is published in Journal of the American Chemical Society.The article was published on 1979-06-01. It has received 134 citations till now. The article focuses on the topics: X-ray crystallography & Carbon.read more
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Transition-metal-mediated dearomatization reactions.
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Chromium arene complexes in organic synthesis
TL;DR: This chemistry is overviewed in this tutorial review, giving special attention to the most recent and outstanding contributions in the area.
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A novel oxidative azidation of aromatic compounds with hypervalent iodine reagent, phenyliodine(III) bis(trifluoroacetate) (PIFA) and trimethylsilyl azide
TL;DR: A novel and useful method for the azidation of aromatic compounds by the reaction of hypervalent iodine reagent, phenyliodine(III) bis(trifluoroacetate) (PIFA) in 1,1, 1,3, 3,3-hexafluoro-2-propanol followed by treatment of trimethylsilyl azide (TMSA) was developed.
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Electrophilic reactivity of coordinated cyclic π-hydrocarbons
TL;DR: In this article, the electrophilic properties of cyclic dienyl and triene complexes are examined and the mechanistic aspects of these reactions are discussed with regard to electrophiles and nucleophilic reactivity, regiochemistry, stereochemistry, and detailed reaction pathways.