Journal ArticleDOI
Five- and Six-coordinated Cobalt(II), Nickel(II), Copper(II), and Zinc(II) Complexes of the Pentadentate Schiff Base Ligands N,N′-bis[(2-hydroxy-5-Y-phenyl)phenylmethylene]-4-azaheptane-1,7-diamine (Y = Chloro Or Methyl) and N,N′-bis[(5-chloro-2-hydroxyphenyl)phenylmethylene]-4-thiaheptane-1,7- Diamine
Reads0
Chats0
About:
This article is published in Inorganic Chemistry.The article was published on 1977-07-01. It has received 27 citations till now. The article focuses on the topics: Diamine & Schiff base.read more
Citations
More filters
Journal ArticleDOI
Synthesis, crystal structures, magnetic properties and catecholase activity of double phenoxido-bridged penta-coordinated dinuclear nickel(II) complexes derived from reduced Schiff-base ligands: mechanistic inference of catecholase activity
Apurba Biswas,Lakshmi Kanta Das,Michael G. B. Drew,Guillem Aromí,Patrick Gamez,Patrick Gamez,Ashutosh Ghosh +6 more
TL;DR: Kinetic data analysis following Michaelis-Menten treatment reveals that the catecholase activity of the complexes is influenced by the flexibility of the ligand and also by the geometry around the metal ion.
Journal ArticleDOI
TiCp2Cl-catalyzed living radical polymerization of styrene initiated by oxirane radical ring opening.
TL;DR: Epoxides and paramagnetic early transition metal complexes are introduced as two new classes of initiators and catalysts, respectively, for living radical polymerizations, providing convenient access to alcohol chain ends, suitable for further transformations.
Journal ArticleDOI
Bis(tetramethylcyclopentadienyl)titanium chemistry. Molecular structures of [(C(5)HMe(4))(mu-eta(1) : eta(5)-C(5)Me(4))Ti](2) and [(C(5)HMe(4))(2)Ti]N-2(2)
JM deWolf,R Blaauw,A. Meetsma,Jan H. Teuben,Róbert Gyepes,[No Value] Varga,Karel Mach,N Veldman,A.L. Spek +8 more
TL;DR: In this paper, a bridging metalated tetramethylcyclopentadienyl ligand was used to give the titanocene (C(5)HMe(4))(2)TiH (5), synthesized by hydrogenolysis of 2 or 3, reacts with N-2 to form the dinuclear Ti(II) dinitrogen compound.
Journal ArticleDOI
Metal complexes with macrocyclic ligands. Part XIX. Synthesis and Cu2+-complexes of a series of 12-, 14- and 16-membered cis- and trans-N2S2-macrocycles
TL;DR: A series of 12-, 14-, and 16-membered N2S2-macrocycles with cis and trans-arrangement of the heteroatoms have been synthesized by high-dilution cyclization and subsequent reduction of the amides with B2H6.
Journal ArticleDOI
Solvent-templated supramolecular isomerism in 2D coordination polymer constructed by NiII2CoII nodes and dicyanamido spacers: drastic change in magnetic behaviours
TL;DR: Variable-temperature magnetic susceptibility measurements revealed that this supramolecular isomerism led to a drastic transition from spin-frustrated antiferromagnetism for 1a to a dominant ferromagnetic behaviour for 1b.