Journal ArticleDOI
Gadolinium sesquichloride, an unusual example of metal-metal bonding
Donald A. Lokken,John D. Corbett +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1970-03-01. It has received 19 citations till now. The article focuses on the topics: Gadolinium.read more
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Condensed Metal Clusters
TL;DR: In the case of the reduced halides of the lanthanoids as discussed by the authors, the metal-metal bonds are linked together by metal clusters of the same type, which can be seen as a way of connecting the two types of structures.
Journal ArticleDOI
Kondensierte Metall‐Cluster
TL;DR: The Ubergangs metallreiche Verbindungen mit p-elementen (3. bis 6. Hauptgruppe) sind ahnlich wie die niederen Halogenide dieser Metalle aus gleichartigen Metall-Clustern aufgebaut as discussed by the authors.
Book ChapterDOI
Chapter 100 Metal-rich halides: Structure, bonding and properties
Journal ArticleDOI
Metallreiche Verbindungen der Seltenen Erden Gd2Cl3, Gd2Br3 und Tb2Cl3
TL;DR: In this article, the authors discuss the relationship between Gd2Br3 and Tb2Cl3 in terms of a conservation of a mean bond order of the MM bonds.
Journal ArticleDOI
Chains of [RE6] Octahedra Coupled by (NCN) Links in the Network Structure of RE2Cl(CN2)N. Synthesis and Structure of Two Novel Rare Earth Chloride Carbodiimide Nitrides with Structures Related to the RE2Cl3 Type
TL;DR: Single crystal X-ray diffraction analyses revealed that 1 and 2 crystallize isotypic in an orthorhombic system and are surprisingly stable toward air and water.
Related Papers (5)
Rare earth metal-metal halide systems. XV. Crystal structure of gadolinium sesquichloride. Phase with unique metal chains
Donald A. Lokken,John D. Corbett +1 more
Metallreiche Verbindungen der Seltenen Erden Gd2Cl3, Gd2Br3 und Tb2Cl3
Rare Earth Metal-Metal Halide Systems. VII. The Phases Gadolinium 1.6-Chloride and Gadolinium Diiodide
Jack E. Mee,John D. Corbett +1 more