Journal ArticleDOI
Heterobimetallic Bi(III)−Ti(IV) Coordination Complexes: Synthesis and Solid-State Structures of BiTi4(sal)6(μ-OiPr)3(OiPr)4, and the Cyclic Isomers Bi4Ti4(sal)10(μ-OiPr)4(OiPr)4 and Bi8Ti8(sal)20(μ-OiPr)8(OiPr)8
TLDR
The compositional and structural parameters from the single crystal studies indicate that complexes 2 and 3 may represent sequential steps in a ligand exchange process between the two metal species, while the reactivity patterns that were observed provide clues about the solution state structure of bismuth(III) salicylate itself.Abstract:
The reaction of a 1:2 mixture of bismuth(III) salicylate with titanium(IV) isopropoxide in refluxing toluene has been investigated and found to proceed with ligand exchange to produce the new heter...read more
Citations
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From molecules to bismuth oxide-based materials: Potential homo- and heterometallic precursors and model compounds
TL;DR: In this article, a review of the potential of bismuth-containing heterometallic oxides is presented together with feasible applications of the latter, and a variety of structurally related high-nuclearity molecular Bismuth oxo clusters are discussed that serve as model compounds.
Journal ArticleDOI
Towards a Structural Understanding of the Anti‐Ulcer and Anti‐Gastritis Drug Bismuth Subsalicylate
Journal ArticleDOI
A Series of Metal–Organic Frameworks Based on Different Salicylic Derivatives and 1,1′-(1,4-Butanediyl)bis(imidazole) Ligand: Syntheses, Structures, and Luminescent Properties
TL;DR: Zn2(L1)2(biim-4)(H2O) as discussed by the authors showed the same 3-connected 103-ths net, and showed a meso-helical chain structure.
Journal ArticleDOI
Polynuclear Bismuth-Oxo Clusters: Insight into the Formation Process of a Metal Oxide
TL;DR: The reaction of the bismuth silanolates with water has been studied and the solid-state structures of [Bi22O26(OSiMe2tBu)14] (9) and beta-Bi2O3 (2) are presented, which gave polynuclear bism Ruth-oxo clusters whereas amorphous bismUTH-oxi(hydroxy) silanolate clusters were obtained when an excess of water was used in the hydrolysis reaction.
Journal ArticleDOI
Structural Diversity of Metal–Organic Materials Containing Bismuth(III) and Pyridine-2,5-Dicarboxylate
TL;DR: In this paper, three new metal-organic materials containing bismuth and pyridine-2,5-dicarboxylate (pydc) have been synthesized by hydro-and solvothermal methods and have been characterized by single crystal X-ray diffraction.
References
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Journal ArticleDOI
NMR Chemical Shifts of Common Laboratory Solvents as Trace Impurities.
TL;DR: 1H and 13C chemical shifts of what are, in the authors' experience, the most popular “extra peaks” in a variety of commonly used NMR solvents are collected, in the hope that this will be of assistance to the practicing chemist.
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A New High-TcOxide Superconductor without a Rare Earth Element
TL;DR: In this paper, a new high-Tc oxide superconductor of the BiSrCa-Cu-O system without any rare earth element was discovered, which has Tc of about 105 K, higher than that of YBa2Cu3O7 by more than 10 K.
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Selective Preparation of Monoclinic and Tetragonal BiVO4 with Scheelite Structure and Their Photocatalytic Properties
TL;DR: In this article, the photocatalytic activity of tetragonal BiVO4 for O2 evolution from an aqueous AgNO3 solution under visible light irradiation was negligible.
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Chimie Douce Approaches to the Synthesis of Metastable Oxide Materials
TL;DR: In this article, a review of the emerging chimie douce (soft-chemical) routes which enable synthesis of a wide variety of metastable oxide materials is presented, and a distinction is made between topochemical and onomatopoetically routes.
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Some trends in the design of homo- and heterometallic molecular precursors of high-tech oxides
TL;DR: In this paper, the development of new materials for the technological demands requires chemical routes, in the case of oxides mostly being sol-gel or CVD processing, for their elaboration.