Journal ArticleDOI
Highly selective reducing agents. Reduction of nitrobenzene to aniline in the presence of aldehydes, alkyl halides, and acid halides.
Reads0
Chats0
TLDR
Although the anionic hydride [HFe(CO) 4 ] − is capable of reducing ketones and aldehydes under acidic conditions, it also selectively reduces nitrobenzene to aniline, even in the presence of benzaldehyde, benzyl chloride, or benzoyl chloride as discussed by the authors.About:
This article is published in Tetrahedron Letters.The article was published on 1988-01-01. It has received 7 citations till now. The article focuses on the topics: Aniline & Nitrobenzene.read more
Citations
More filters
Book ChapterDOI
Reduction of Nitro and Nitroso Compounds
TL;DR: Aromatic nitro compounds are the usual starting materials for commercial applications, but aliphatic compounds exhibit a greater diversity of chemical behavior under reducing conditions as mentioned in this paper, and are frequently encountered during the reduction of Nitro compounds, such as hydroxylamines, oximes, amines, nitrones, ketones and silyl nitronates.
Journal ArticleDOI
Reductive N-acylation of nitroarenes by Fe3+-montmorillonite
M. Lakshmi Kantam,Kalluri V. S. Ranganath,Mutyala Sateesh,Bojja Sreedhar,Boyapati Manoranjan Choudary +4 more
TL;DR: In this paper, the Nacylation of nitroarenes to anilides in moderate to good yields in the presence of carboxylic acid anhydrides using a recyclable heterogeneous catalyst, Fe3+-montmorillonite, prepared from inexpensive materials is achieved in a single pot.
Journal ArticleDOI
Potassium tetracarbonylhydridoferrate : A reagent for the selective reduction of carbonyl groups
TL;DR: KHFe(CO)4 is an efficient reagent for the reduction of electron-deficient ketones (trifluoroacetophenone) and for the selective mono-reduction of the keto group of α-ketocarbonyl compounds such as benzil, methyl benzoylformate, N-methylisatine and methyl pyruvate as discussed by the authors.
References
More filters
Journal ArticleDOI
Selective hydrogenation of .alpha.,.beta.-unsaturated carbonyl compounds via hydridoiron complexes
R. Noyori,I. Umeda,T. Ishigami +2 more
Journal ArticleDOI
Anionic group 6 transition-metal carbonyl hydrides as reducing agents. ketones, aldehydes, and epoxides
TL;DR: Etude des proprietes reductrices des complexes suivants: HM(CO) 5 − et cis-HM(CO), 4 P(OCH 3 ) 3 − (M=Cr, W) as mentioned in this paper.
Journal ArticleDOI
Solution structure and reactivity of hydridoiron tetracarbonyl anion, [HFe(CO)4]-
Journal ArticleDOI
Reaction of cyclic .beta.-halo .alpha.,.beta.-unsaturated ketones with cuprate reagents. New, efficient synthesis of .beta.-alkyl .alpha.,.beta.-unsaturated ketones
Edward Piers,Isao Nagakura +1 more
TL;DR: In this article, the 3-Brom-2-cyclohexenon (I) reagiert with den Alkylphenylthio-lithiumcupraten (II) in hohen Ausbeuten zu den 3-Alkyl-2cycloenonen (III).
Journal ArticleDOI
Relative reactivity and mechanistic studies of the hydride-transfer reagents HM(CO)4L− (M=Cr, W; L=CO, PR3)
S. C. Kao,Cris Tina. Spillett,Carlton E. Ash,Richard. Lusk,Yong-Kwang Park,Marcetta Y. Darensbourg +5 more
TL;DR: In this article, a serie d'hydrures de metaux de transition is compared, selon leurs aptitudes a reduire les hydrocarbures halogenes en hydro carbures.
Related Papers (5)
AlNiCl2.6H2OTHF: A new, mild and neutral system for selective reduction of organic functional groups
Bhabani K. Sarmah,Nabin C. Barua +1 more