Journal ArticleDOI
Highly Stereoselective Aldol Condensation Using an Enantioselective Chiral Enolate
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This article is published in Angewandte Chemie.The article was published on 1980-07-01. It has received 181 citations till now. The article focuses on the topics: Aldol condensation & Enantioselective synthesis.read more
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Double Asymmetric Synthesis and a New Strategy for Stereochemical Control in Organic Synthesis
TL;DR: In this article, it is shown that double asymmetric induction can be analyzed in terms of the single asymmetric reactions of each of the two chiral reactants, and a new strategy based on this rule for the predictable creation of new chiral centers is discussed and the use of this strategy for the synthesis of sugars and macrolides is presented.
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The Unambiguous Specification of the Steric Course of Asymmetric Syntheses
Dieter Seebach,Vladimir Prelog +1 more
TL;DR: In this article, the relative topicity of approach of reactants is defined as like {Ik} and unlike (ul) if the corresponding descriptor pairs are Re*,Re*. or R*,Re*, and Re*,Si* or R*)Si*, respectively.
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Diastereogenic Addition of Crotylmetal Compounds to Aldehydes
TL;DR: In this article, the authors proposed a stereoselective CC bond forming reaction to obtain a diastereomeric adduct from E- or Z-crotyl compounds.
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Stereoselective reduction of β hydroxyketones to 1,3-diols highly selective 1,3-asymmetric induction via boron chelates
Koichi Narasaka,Fong-Chang Pai +1 more
TL;DR: In this article, the reduction of acyclic β-hydroxy ketones via boron chelates via asymmetric induction can be achieved in a highly selective manner.
Journal ArticleDOI
Doppelte Stereodifferenzierung und eine neue Strategie zur Stereokontrolle in der Organischen Synthese
TL;DR: In this article, an einfach asymmetrischen Reaktionen eines beiden chiralen Reaktanten with einem achiralen Partner analysiert werden kann.