Journal ArticleDOI
Enantioselective aldol condensations. 2. Erythro-selective chiral aldol condensations via boron enolates
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This article is published in Journal of the American Chemical Society.The article was published on 1981-04-01. It has received 1282 citations till now. The article focuses on the topics: Aldol reaction & Enantioselective synthesis.read more
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Weak coordination as a powerful means for developing broadly useful C-H functionalization reactions.
TL;DR: The motivation for studying Pd-catalyzed C-H functionalization assisted by weakly coordinating functional groups is discussed, and efforts to bring reactions of this type to fruition are chronicle.
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1,2-Amino Alcohols and Their Heterocyclic Derivatives as Chiral Auxiliaries in Asymmetric Synthesis
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Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity
TL;DR: This critical review discusses historical and contemporary research in the field of transition metal-catalyzed carbon-hydrogen (C-H) bond activation through the lens of stereoselectivity, placing an emphasis on reactions that are (or may soon become) relevant in the realm of organic synthesis.
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Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents
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Double Asymmetric Synthesis and a New Strategy for Stereochemical Control in Organic Synthesis
TL;DR: In this article, it is shown that double asymmetric induction can be analyzed in terms of the single asymmetric reactions of each of the two chiral reactants, and a new strategy based on this rule for the predictable creation of new chiral centers is discussed and the use of this strategy for the synthesis of sugars and macrolides is presented.