Journal ArticleDOI
Hydrolysis of toxic organophosphorus compounds by o-iodosobenzoic acid and its derivatives
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TLDR
In the presence of the following esters: trimethyl-1,2,2 propyle and isopropyle de l'acide methyl phosphonofluoridique (soman et sarin respectivement), du N,N-dimethyl phosphoramidocyanidate d'ethyle (tabum) and du (diethyl nitro-4 phenyl) phosphate dans des solutions aqueuses micellaires de chlorure de (palmityl trimethyl) ammonium, en presence d'acides iodosAbstract:
Hydrolyse des esters trimethyl-1,2,2 propyle et isopropyle de l'acide methyl phosphonofluoridique (soman et sarin respectivement), du N,N-dimethyl phosphoramidocyanidate d'ethyle (tabum) et du (diethyl nitro-4 phenyl) phosphate dans des solutions aqueuses micellaires de chlorure de (palmityl trimethyl) ammonium, en presence d'acide iodosyl-«2» benzoiqueread more
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Journal ArticleDOI
Phosphorolytic reactivity of o-iodosylcarboxylates and related nucleophiles.
Journal ArticleDOI
Chemical and Biological Protection and Detection in Fabrics for Protective Clothing
Heidi Schreuder-Gibson,Quoc Truong,John E. Walker,Jeffery R. Owens,Joseph D. Wander,Wayne E. Jones +5 more
TL;DR: In this paper, the authors proposed new technologies being built into advanced fabrics for enhanced chemical and biological protection include selectively permeable membranes, reactive nanoparticles, reactive nanofibers, biocidal fabric treatments, and conductive-polymer indicators on optical fibers.
Journal ArticleDOI
Formation of single-bonded (C60-)2 and (C70-)2 dimers in crystalline ionic complexes of fullerenes.
Dmitri V. Konarev,Salavat S. Khasanov,Gunzi Saito,Akihiro Otsuka,Yukihiro Yoshida,Rimma N. Lyubovskaya +5 more
TL;DR: It is shown that C(60)(.-) exists as a single-bonded diamagnetic (C60-)2 dimer in 1, 2, 4, 5, and 8 at low temperatures and only above 250-360 K.
Journal ArticleDOI
Sarin: health effects, metabolism, and methods of analysis
TL;DR: Toxicity from sarin significantly increased following concurrent exposure to other chemicals such as pyridostigmine bromide, and further research to examine effects of sarin on the cellular and the molecular levels, gene transcription, endocrine system as well as its long-term impact is needed.
Journal ArticleDOI
The maximin principle of pi-radical packings.
TL;DR: In this paper, a two-term model is proposed for hydrocarbon and N-containing π-radicals which are in close contact with one another, and the model is applied to dimers where intermolecular contacts are closer than <0.95 × the sum of the atomic van der Waals radii.