Journal ArticleDOI
Influence of structure on the rate of thermal rearrangement of aryl propargyl ethers to the chromenes. Gem-dimethyl effect
Morton Harfenist,Edna Thom +1 more
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This article is published in Journal of Organic Chemistry.The article was published on 1972-03-01. It has received 61 citations till now. The article focuses on the topics: Propargyl & Aryl.read more
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Gem-Disubstituent Effect: Theoretical Basis and Synthetic Applications
Michael E. Jung,Grazia Piizzi +1 more
TL;DR: A comparison study of the effects of gem-Dialkyl Substitution in Drug Design on the Formation and Stability of Inorganic and Organometallic Complexes and their implications for synthetic chemistry and drug design.
Journal ArticleDOI
Catalytic Synthesis of 2H-Chromenes
TL;DR: This review gives an up-to-date overview of different catalytic methodologies developed for the synthesis of 2H-chromenes and is structured around the three main approaches applied in catalytic 2h-chromene synthesis: catalysis with (transition) metals, metal-free Bronsted and Lewis acid/base catalysis, and enantioselective organo-catalysis.
Journal ArticleDOI
Enzymatic Basis of Ribosomal Peptide Prenylation in Cyanobacteria
TL;DR: It is shown that the Claisen rearrangement drives phenolic C-prenylation in at least one case, suggesting that this route should be reconsidered as a mechanism for the biosynthesis of prenylated phenolic compounds.
Journal ArticleDOI
Improved synthesis of aryl 1,1-dimethylpropargyl ethers
Jollie D. Godfrey,Richard H. Mueller,Thomas C. Sedergran,Nachimuthu Soundararajan,Vincent J. Colandrea +4 more
TL;DR: An efficient, general, and practical synthesis of aryl 1,1-dimethylpropargyl ethers has been developed in this paper, which can be used for a wide range of applications.
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