Journal ArticleDOI
Influence of the Reaction Conditions and Catalytic Properties on the Liquid-Phase Hydrodechlorination of Chlorobenzene over Palladium-Supported Catalysts: Activity and Deactivation
María A. Aramendía,Victoriano Borau,I.M. Garcı́a,César Jiménez,F. Lafont,Alberto Marinas,José M. Marinas,Francisco J. Urbano +7 more
TLDR
In this paper, the palladium-supported catalysts were used for the liquid-phase hydrodechlorination of chlorobenzene with molecular hydrogen in the presence of chloride ions.About:
This article is published in Journal of Catalysis.The article was published on 1999-10-25. It has received 144 citations till now. The article focuses on the topics: Chlorobenzene & Chloride.read more
Citations
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Journal ArticleDOI
Metal-mediated reductive hydrodehalogenation of organic halides.
Journal ArticleDOI
Critical Review of Pd-Based Catalytic Treatment of Priority Contaminants in Water
Brian P. Chaplin,Martin Reinhard,William F. Schneider,Christoph Schüth,John R. Shapley,Timothy J. Strathmann,Charles J. Werth +6 more
TL;DR: This review critically analyzes the published research in the area of Pd-based catalytic reduction of priority drinking water contaminants, and identifies key research areas that should be addressed.
Journal ArticleDOI
Hydrogenolysis of organohalogen compounds over palladium supported catalysts
TL;DR: In this paper, the experimental procedures for catalytic hydrodehalogenation are reviewed; the hydrogen source can be either molecular hydrogen or a hydrogen donor in the so-called hydrogen-transfer hydrogenolysis.
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Poisoning and deactivation of palladium catalysts
TL;DR: In this article, the major causes for deactivation and premature degradation of palladium catalysts are briefly summarised, including particle growth for various reasons, coke deposition and coke transformation, the influence of the support material on long term stability and modifications at the palladium surface itself such as valency changes or the formation of simple but stable molecular surface species.
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The synthesis of highly dispersed noble and base metals on silica via strong electrostatic adsorption: I. Amorphous silica
Ling Jiao,John R. Regalbuto +1 more
TL;DR: In this paper, a series of silica-supported noble and base metal catalysts prepared by strong electrostatic adsorption (SEA) was compared with the traditional incipient wetness impregnation (IWI) method.
References
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Journal ArticleDOI
Adsorption of Gases in Multimolecular Layers
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Conversion of chlorobenzene over palladium and rhodium catalysts of widely varying dispersion
TL;DR: In this paper, the authors investigated the kinetics of hydrodechlorination of chlorobenzene over Pd Al 2 O 3 and Rh Al 2O 3 catalysts of varying dispersion and proposed a reaction scheme which is formally analogous to the Mars-van Krevelen mechanism for the oxidation of hydrocarbons.
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Conversion under hydrogen of dichlorodifluoromethane over supported palladium catalysts
TL;DR: In this paper, the conversion of difluorodichloromethane has been studied in the gas phase between 433 and 523 K at atmospheric pressure aver Pd black and Pd supported on alumina, graphite, or AlF3.
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Magnesium Oxides as Basic Catalysts for Organic Processes: Study of the Dehydrogenation–Dehydration of 2-Propanol
María A. Aramendía,Victoriano Borau,César Jiménez,José M. Marinas,A. Porras,Francisco J. Urbano +5 more
TL;DR: In this article, the reactivity of various magnesium oxides in the gas-phase dehydrogenation-dehydration of 2-propanol was studied by using a tubular flow reactor.