Journal ArticleDOI
Metal-mediated reductive hydrodehalogenation of organic halides.
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This article is published in Chemical Reviews.The article was published on 2002-10-09. It has received 767 citations till now.read more
Citations
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Organic Photoredox Catalysis
TL;DR: An overview of the basic photophysics and electron transfer theory is presented in order to provide a comprehensive guide for employing this class of catalysts in photoredox manifolds.
Journal ArticleDOI
Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation
TL;DR: This review focuses on Rh-catalyzed methods for C-H bond functionalization, which have seen widespread success over the course of the last decade and are discussed in detail in the accompanying articles in this special issue of Chemical Reviews.
Journal ArticleDOI
Solar Synthesis: Prospects in Visible Light Photocatalysis
TL;DR: A variety of reaction types have now been shown to be amenable to visible light photocatalysis via photoinduced electron transfer to or from the transition metal chromophore, as well as energy-transfer processes.
Journal ArticleDOI
C-F bond activation in organic synthesis.
Hideki Amii,Kenji Uneyama +1 more
TL;DR: Organic fluorine compounds have received a great deal of interest and attention from the scientists involved in diverse fields of science and technology and not only C-F bond formation but also selective C-f bond activation have become current subjects of active investigation from the viewpoint of effective synthesis of fluoroorganic compounds.
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Recent Advances in the Catalytic Oxidation of Volatile Organic Compounds: A Review Based on Pollutant Sorts and Sources.
TL;DR: This Review systematically documents the progresses and developments made in the understanding and design of heterogeneous catalysts for VOC oxidation over the past two decades and addresses in detail how catalytic performance is often drastically affected by the pollutant sources and reaction conditions.
References
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Stratospheric sink for chlorofluoromethanes: chlorine atomc-atalysed destruction of ozone
Mario J. Molina,F. S. Rowland +1 more
TL;DR: Chlorofluoromethanes are being added to the environment in steadily increasing amounts as discussed by the authors and these compounds are chemically inert and may remain in the atmosphere for 40 to 150 years, and concentrations can be expected to reach 10 to 30 times present levels.
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Large losses of total ozone in Antarctica reveal seasonal ClOx/NOx interaction
TL;DR: In this article, it was shown that the very low temperatures which prevail from midwinter until several weeks after the spring equinox make the Antarctic stratosphere uniquely sensitive to growth of inorganic chlorine, ClX, primarily by the effect of this growth on the NO2/NO ratio.
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Synthesizing Nanoscale Iron Particles for Rapid and Complete Dechlorination of TCE and PCBs
Chuan-Bao Wang,Wei-xian Zhang +1 more
TL;DR: In this article, an efficient method of synthesizing nanoscale (1−100 nm) iron and palladized iron particles is presented, which is characterized by high surface area to volume ratios and high reactivities.
Journal ArticleDOI
Reductive Dehalogenation of Chlorinated Methanes by Iron Metal
TL;DR: The reduction of chlorinated methanes in batch model systems appears to be coupled with oxidative dissolution (corrosion) of the iron through a largely diffusion-limited surface reaction.
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Enhanced Degradation of Halogenated Aliphatics by Zero‐Valent Iron
TL;DR: In this article, the degradation process appeared to be pseudo first-order with respect to the organic compound, with the rate constant appearing to be directly proportional to the surface area to volume ratio and increasing with increasing degree of chlorination.