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Journal ArticleDOI

Infrared matrix isolation studies of the 1:1 complexes of chlorine fluoride with nitrogen bases in argon and nitrogen matrices

Nicholas P. Machara, +1 more
- 01 May 1988 - 
- Vol. 92, Iss: 9, pp 2439-2442
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This article is published in The Journal of Physical Chemistry.The article was published on 1988-05-01. It has received 17 citations till now. The article focuses on the topics: Chlorine fluoride & Matrix isolation.

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Journal ArticleDOI

Cooperativity between the halogen bond and the hydrogen bond in H3N...XY...HF complexes (X, Y=F, Cl, Br).

TL;DR: Results indicate significant cooperativity between the halogen and hydrogen bonds in these complexes, much greater than that between hydrogen bonds.
Journal ArticleDOI

Charge-Transfer Complexes between NH3 and the Halogens F2, ClF, and Cl2: An ab Initio Study on the Intermolecular Interaction

TL;DR: In this article, the ground-state properties of the charge tranfer complexes formed between NH3 and the halogens F2, ClF, and Cl2 were investigated systematically with the aid of ab initio calculations.
Journal ArticleDOI

Präreaktive Komplexe der Dihalogene XY mit Lewis‐Basen B in der Gasphase: eine systematische Studie der Halogen‐Analoga B⋅⋅⋅XY der Wasserstoffbrückenbindungen B⋅⋅⋅HX

TL;DR: In this article, the authors describe the abgebildeten Strukturen von Oxiran and ClF in der Gasphase, in denen B eine einfache Lewis-Base, XY ein Homo- oder Heterodihalogen-and HX ein Halogenwasserstoffmolekul ist.
Journal ArticleDOI

Effects of fluorine substitution on hydrogen bond interactions

TL;DR: The effect of fluorine substitution on a series of hydrogen-bonded (HB) systems has been studied with the aid of theoretical ab initio methods in this article, which indicates a 0.1 − 1 − 1−kcal/mol increase for the interaction energy.
Journal ArticleDOI

Main group coordination chemistry at low temperatures: A review of matrix isolated Group 12 to Group 18 complexes

TL;DR: The available data on main group (Groups 12-18) Lewis acid base, donor-acceptor, charge transfer and van der Waals complexes stabilised by matrix isolation techniques are presented, tabulated and evaluated in conjunction with data from complementary gas phase experiments and computational chemistry as discussed by the authors.
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