Journal ArticleDOI
Inhibition of the anthraquinone photosensitised oxidation of polypropylene by a hindered piperidine stabiliser: A spectroscopic study
TLDR
A hindered piperidine stabiliser, bis{2,2,6,6-tetramethyl-4-piperidinyl}-sebacate, has been found to inhibit the photo-sensitising effect of anthraquinone in polypropylene on flash photolysis in n -hexane solution transient formation due to the semi-quinone radical (AH·) at 370 nm and subsequent formation of the hydroquinone (9,10-dihydroxyanthracene (AH 2 ) were found to be effectively inhibitedAbout:
This article is published in Polymer Degradation and Stability.The article was published on 1980-10-01. It has received 7 citations till now. The article focuses on the topics: Nitroxyl & Piperidine.read more
Citations
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Journal ArticleDOI
Degradation and stabilisation of styrene–ethylene–butadiene–styrene (SEBS) block copolymer
Norman S. Allen,Michele Edge,Arthur Wilkinson,C.M. Liauw,Despina Mourelatou,Juan A. Barrio,Maria A Martı́nez-Zaporta +6 more
TL;DR: The degradation of hydrogenated poly[styrene b -butadiene- b -styrene] has been studied using a variety of analytical and spectroscopic methods including thermal analysis, UV, luminescence and FTIR spectroscopy coupled with crosslinking and hydroperoxide analysis in order to understand the nature of the processes involved as mentioned in this paper.
Journal ArticleDOI
The use of lactic acid-based hot melt adhesive in the industrial lamination process
TL;DR: The suitability of the lactic acid-based hot melt adhesive formulation for the glue lamination process was evaluated in this paper, where a copolymer consisting of poly( l -lactide) and poly(e-caprolactone) with molar ratio 81:19, respectively.
Journal ArticleDOI
Photo-stabilising action of metal chelate stabilisers in polypropylene: Part VII—Additive interactions
TL;DR: In this article, the interaction of four metal chelates (Cyasorb UV 1084, Irganox 1425, Irgastab 2002 and Sanduvor NPU) with five commercial pigments, anatase and rutile titanium dioxide, cadmium yellow, Vynamon Blue B and Monolite Yellow G, was examined using infra-red spectroscopy.
Journal ArticleDOI
Photostabilising effect of bis(hindered piperidine) compounds: Part I—In photo-oxidative degradation of cis-1,4-poly(butadiene)
TL;DR: The photostabilizing effect of three commercially available bis(hindered piperidines): Tinuvin 144 (bis(1,2,2-6,6-pentamethyl-4-piperidinyl)-2-n-butyl-2-(3,5-di-tert,butyl)-4-hydroxy-benzyl) malonate; tinuvin 292(bis( 1,2.2.6, 6, 6-pentamide-4)-sebacate) and tinuvan 770 (
Journal ArticleDOI
Factors influencing the photofading of commercial anthraquinone dyes in solution
TL;DR: In this paper, the photofading of two anthraquinone dyes has been studied in aqueous solution using ultraviolet-visible absorption spectroscopy and flash photolysis.
References
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Book
Photochemistry of man-made polymers
John F. McKellar,Norman S. Allen +1 more
TL;DR: Ge Geoffroy and Mark S. Wrighton as mentioned in this paper presented the utter variation of this ebook in ePub, doc, DjVu, PDF, txt formats, and they had a link to the site where you may load or reading online.
Journal ArticleDOI
Some aspects of stabilization of polymers against light
H. J. Heller,H. R. Blattmann +1 more
TL;DR: In this paper, different mechanisms for the protection of polymers against photodegradation are discussed, and evidence is presented that this rapid nonradiative deactivation cannot be explained very satisfactorily by a simple 'enol-keto'-equilibrium in the first excited singlet state only.
Journal ArticleDOI
Synthesis and Reactions of Stable Nitroxyl Radicals II. Reactions1
Rozantsev Eduard G,V. D. Sholle +1 more
Journal ArticleDOI
The Photooxidative Degradation of Polypropylene. Part II. Photostabilization Mechanisms
D. J. Carlsson,D. M. Wiles +1 more
TL;DR: A comprehensive list of UV-stabilizers and stabilizer structures have appeared in the recent literature [1, 4] as mentioned in this paper, which has led to the development of many UV stabilizers for general use in films, fibers, and moldings.
Journal ArticleDOI
Polyolefin photo-stabilisation mechanisms. Reactions of tetramethylpiperidine derivatives in model systems☆
TL;DR: The relative rate of cyclohexyl radical scavenging by oxygen or 4-oxo-2,2,6,6-tetramethylpiperidino-Noxyl has been measured at 25°C, together with the relative rates of cycloenyl peroxy radical attack on cycloenane or substituted hydroxylamines derived from 2,2.6, 6, 6-to-6-toothpiperidine derivatives.