Journal ArticleDOI
Intercalation of alkanols and alkylamines in insoluble acid salts of tetravalent metals having a layered structure of γ-type
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In this article, it was shown that only 50 or 66% of the groups, present in the exchangers, interact with the amino groups of the guest molecules, owing to the closeness of the active sites present on the faces of the layers.About:
This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1981-01-01. It has received 58 citations till now. The article focuses on the topics: Bilayer & Monolayer.read more
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Layered and pillared metal(IV) phosphates and phosphonates
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Recent progress in the intercalation chemistry of layered α-zirconium phosphate and its derivatives, and future perspectives for their use in catalysis
TL;DR: In this paper, a brief discussion of the present status of knowledge of the mechanism of intercalation processes in α-zirconium phosphate, recent developments particularly in the synthesis of new layered materials with α-structures are examined.
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Mn2(H2O)[O2C(CH2)nCO2]2 (n = 3−12): Replication of an Inorganic Monolayer in Three-Dimensional (Dicarboxylato)manganese(II)
TL;DR: A series of manganese α,ω-dicarboxylates, Mn2(H2O)[O2C(CH2)nCO2]2 (n = 3−12), were synthesized as single crystals or polycrystallines by the hydrothermal reaction of MnCl2 with the corresponding diccarboxylic acid in the presence of base as discussed by the authors.
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Solvothermal Ion Exchange of Aliphatic Dicarboxylates into the Gallery Space of Layered Double Hydroxides Immobilized on Si Substrates
TL;DR: In this paper, high-ordered Mg/Al-based layered double hydroxide (LDH) nanocrystals on Si substrates were successfully obtained by ultrasonic treatment in organic solvents.
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Pillared Derivatives of γ-Zirconium Phosphate Containing Nonrigid Alkyl Chain Pillars
TL;DR: Pillared derivatives of γ-zirconium phosphate, having the general formula ZrPO4[O 2P(OH)2]1-x[O2POH−(CH2)n−HOPO2]x/2·mH2O (n = 4, 6, 8, 10, 12, and 16), were prepared by soft topotactic reactions between colloidal dispersions of exfoliated lamellae of ZrPPO4 [O 2 P(OH]2]·2H 2O and 1
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New crystalline phases of zirconium phosphate possessing ion-exchange properties
TL;DR: In this article, the preparation of two new crystalline zirconium phosphates, Zr(HPO4)2 and Zr[H20]2 · 2H2O, is reported.
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Kink‐Block and Gauche‐Block Structures of Bimolecular Films
TL;DR: In this paper, the structure of monomolecular and bimolecular films has been investigated in terms of reversible kink-block and gauche-block structures of lipid layers in membranes.
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On the mechanism of ion exchange in zirconium phosphates—XXI Intercalation of amines by α-zirconium phosphate
TL;DR: The intercalation of n -propylamine, n -butylamine and ethylenediamine by the layered compound α-zirconium phosphate has been examined in this paper.
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Formation region and structural model of γ-zirconium phosphate
Shoji Yamanaka,Masami Tanaka +1 more
TL;DR: In this paper, the formation region of γ-zirconium phosphate (γ-ZrP) was determined by using zircinium phosphate gels heated in phosphate solutions with various pH values.
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Synthesis and characterization of the organic derivatives of zirconium phosphate
TL;DR: γ-Zirkoniumphosphat wird beim Tauchen in eine wasrige Losung von Athylenoxid in neue, bis 200°C stabile Phasen mit vergroserten Grundflachenabstanden umgewandelt, die in alkalischer Losung zu den Phosphorsaureestern of Athylenglykol and Zr-hydroxid hydrolysiert werden as mentioned in this paper.