Journal ArticleDOI
Ion pair complex formed between bis(cyclooctatetraenyl)cerium(III) anion and an ether-coordinated potassium cation. Crystal and molecular structure of [K(CH3OCH2CH2)2O][Ce(C8H8)2]
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This article is published in Inorganic Chemistry.The article was published on 1972-12-01. It has received 103 citations till now. The article focuses on the topics: Potassium Cation & Cerium.read more
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Book ChapterDOI
Sodium, Potassium, Rubidium, and Cesium: X-Ray Structurai Analysis of Their Organic Compounds1
TL;DR: In this paper, the published X-ray investigations of organometallic compounds of Na, K, Rb, and Cs have been discussed and many structures through 1985 also are reported.
Journal ArticleDOI
A Novel Network Structure of Organometallic Clusters in the Gas Phase
Atsushi Nakajima,Koji Kaya +1 more
TL;DR: In this article, a beam source with laser vaporization of metal rods and time-of-flight mass spectrometry was used to produce and detect the gas-phase organometallic clusters.
Journal ArticleDOI
Structural criteria for the mode of bonding of organoactinides and -lanthanides and related compounds
TL;DR: In this paper, the authors summarized much of the structural information accumulated during the last ten years, focusing on the unifying structural trends in these compounds and the question of the mode of bonding.
Journal ArticleDOI
New 7r-cyclooctate'I'raenyl and iT-cyclopentadienyl complexes of cerium
TL;DR: In this article, the reduction of Ce(O-i-C~H-I')4 by (C2H5),%Al in the presence of cycloocta- tientraene (COT) yielded (Cshs),.
Journal ArticleDOI
Formally tetravalent cerium and thorium compounds: a configuration interaction study of cerocene Ce(C8H8)2 and thorocene Th(C8H8)2 using energy-adjusted quasirelativistic ab initio pseudopotentials
TL;DR: In this article, large-scale state-averaged multi-configuration selfconsistent field, configuration interaction, averaged coupled-pair functional and spin-orbit configuration interaction calculations have been carried out for the ground states and low-lying excited states of the bis(cyclooctatetraene)f-element sandwich complexes cerocene Ce(C 8 H 8 ) 2 and thorocene Th(C8 H 8 2 ) 2.