Book ChapterDOI
Ion Pairing Effects on Transition Metal Carbonyl Anions
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This article is published in Progress in Inorganic Chemistry.The article was published on 2007-03-09. It has received 65 citations till now. The article focuses on the topics: Molecule & Inorganic compound.read more
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Crystal Engineering and Organometallic Architecture.
Book ChapterDOI
Nucleophilic Activation of Carbon Monoxide: Applications to Homogeneous Catalysis by Metal Carbonyls of the Water Gas Shift and Related Reactions
Peter C. Ford,Andrzej Rokicki +1 more
TL;DR: In this paper, the roles played by certain nucleophile adducts of metal-coordinated carbon monoxide in the stoichiometric and catalytic chemistry of metal carbonyl complexes and relatively recent developments for systems where oxygen or nitrogen bases have been used as the nucleophiles are discussed.
Journal ArticleDOI
Distal and proximal ligand interactions in heme proteins: correlations between C-O and Fe-C vibrational frequencies, oxygen-17 and carbon-13 nuclear magnetic resonance chemical shifts, and oxygen-17 nuclear quadrupole coupling constants in C17O- and 13CO-labeled species.
TL;DR: The results suggest that IR and NMR measurements reflect the same interaction, which is thought to be primarily the degree of pi-back-bonding from Fe d to CO pi* orbitals, as outlined previously.
Book ChapterDOI
Highly Reduced Metal Carbonyl Anions: Synthesis, Characterization, and Chemical Properties
TL;DR: In this article, highly reduced metal carbonyl anions were discussed and the most persuasive chemical evidence for the existence of monohydrides of manganese and rhenium is their high-yield conversion to corresponding dihydrides, which can be isolated as relatively stable crystalline solids.
References
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Silicon-29 NMR study of the surface of silica gel by cross polarization and magic-angle spinning
Gary E. Maciel,Dean W. Sindorf +1 more
Related Papers (5)
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