Journal ArticleDOI
Kinetics of the reaction of HO2 with CH3C(O)O2 in the temperature range 253–368 K
TLDR
In this paper, the authors studied the kinetics of the reaction between HO2 and CH3C(O)O2 radicals in the gas phase at atmospheric pressure between 253 and 368 K.About:
This article is published in Chemical Physics Letters.The article was published on 1989-08-18. It has received 100 citations till now. The article focuses on the topics: Reaction rate constant & Flash photolysis.read more
Citations
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Carboxylic acids in the troposphere, occurrence, sources, and sinks: A review
A. Chebbi,P. Carlier +1 more
TL;DR: In this paper, a synthesis of low molecular weight carboxylic acids in tropospheric aqueous and gaseous phases and in aerosol particles for different environments is presented.
Journal ArticleDOI
Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry
P.D Lightfoot,Richard A. Cox,John Crowley,M Destriau,G. D. Hayman,Michael E. Jenkin,Geert K. Moortgat,F Zabel +7 more
TL;DR: A review of the state of the art in peroxy radical detection can be found in this article, where a number of experimental techniques have been used for the generation and detection of peroxy radicals and products of their reactions.
Journal ArticleDOI
Gas-phase ozone oxidation of monoterpenes: Gaseous and particulate products
TL;DR: In this article, a series of outdoor smog chamber experiments were conducted to investigate both gaseous and particulate products in the ozone oxidation of four monoterpenes: α-pinene, sabinene, β-pinenes, Δ^3-carene, and sabinenes.
Journal ArticleDOI
MOZART, a global chemical transport model for ozone and related chemical tracers: 1. Model description
Guy Brasseur,Didier Hauglustaine,Stacy Walters,Philip J. Rasch,J.-F. Müller,Claire Granier,X. Tie +6 more
TL;DR: In this paper, a new global three-dimensional chemical transport model (called MOZART) was developed in the framework of the NCAR Community Climate Model and aimed at studying the distribution and budget of tropospheric ozone and its precursors.
Journal ArticleDOI
Atmospheric chemistry of small organic peroxy radicals
Geoffrey S. Tyndall,Richard A. Cox,Claire Granier,Robert Lesclaux,Geert K. Moortgat,Michael J. Pilling,A. R. Ravishankara,Timothy J. Wallington +7 more
TL;DR: In this paper, the atmospheric chemistry of the four most abundant organic peroxy radicals (CH3O2, C2H5O2 and CH3C(O)O2) was evaluated.
References
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Journal ArticleDOI
Absolute absorption cross sections of ozone in the 185- to 350-nm wavelength range
Luisa T. Molina,Mario J. Molina +1 more
TL;DR: In this article, the absorption cross sections of ozone have been measured in the wavelength range 185-350 nm and in the temperature range 225-298 K. The absolute ozone concentrations were established by measuring the pressure of pure gaseous samples in the 0.08to 300-torr range, and the UV spectra were recorded under conditions where less than 1 percent of the sample decomposed.
Journal ArticleDOI
Kinetics and mechanism of the photo-oxidation of formaldehyde. 1. Flash photolysis study
Bernard Veyret,Robert Lesclaux,Marie Therese Rayez,J.C. Rayez,Richard A. Cox,Geert K. Moortgat +5 more
TL;DR: In this article, the authors used flash photolysis kinetic spectroscopy to investigate the transient species in the photooxidation of formaldehyde in air and determined the branching ratios for HOCH{sub 2}O{sub2} radical.
Journal ArticleDOI
Absorption spectrum and kinetics of reactions of the acetylperoxy radical
TL;DR: In this paper, the ultraviolet absorption spectrum of the acetylperoxy radical was measured in the range 190-280 nm and the rate constants were derived from computer simulations of the absorption traces obtained at various wavelengths using nonlinear least-squares treatment of multiple time profiles.
Journal ArticleDOI
FTIR study of the kinetics and mechanism for chlorine-atom-initiated reactions of acetaldehyde
Journal ArticleDOI
UV absorption spectra of HO2 and CH3O2 radicals and the kinetics of their mutual reactions at 298 K
TL;DR: In this article, a flash photolysis study of the UV, spectra of HO2 and CH3O2 radicals, obtained by using a calibration technique based on the reaction Cl+NO→NOCl.
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