Journal ArticleDOI
LFERs—III. Correlation of rates of substitution and electron transfer reactions of monohalogenometal complexes with partial charge
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TLDR
In this article, the rates of several substitution and electron transfer reactions of monohalogeno complexes of cobalt(III) and chromium (III) have been correlated successfully with the LFER (1), log k = mδ x + c where k is the rate constant, δ x is partial charge on bound halogen in M X bond and m and c are empirical constants.About:
This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1977-01-01. It has received 2 citations till now. The article focuses on the topics: Partial charge & Reaction rate constant.read more
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Synthesis and Structure of the Polyoxoanion [Si2W23O77(OH)]9-
TL;DR: The reaction of tungstate with the γ-decatungstosilicate anion leads to [Si2W23O77(OH)]9− This anion results from the association of γ]-SiW10O36]8- and γ-[SiW11O39]8]- by a (μ-oxo)ditungstic group.
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Linear free energy relationships and the kinetics of ligand substitutions. Correlation of rate constants with overall stability constants of reactive intermediate species in the stepwise formation of tetracyanonickelate(II) from mono aminocarboxylatonickel (II) complexes
Krishan Kumar,Prem C. Nigam +1 more
TL;DR: A linear free energy relationship is proposed between step-wise rate constants and overall stability constants of the intermediates of the type NiL(CN)x formed in the four step reaction mechanism of CN− with NiL where L denotes aminocarboxylates.
References
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Book
Ligand substitution processes
Cooper H. Langford,Harry B. Gray +1 more
TL;DR: In this article, an approach to classification of ligand substitution reactions is presented, which is adapted to what seem to have emerged as the characteristic features of these reactions and is susceptible to operational tests.
Journal ArticleDOI
Activation parameters and reaction mechanism in octahedral substitution
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