Journal ArticleDOI
Manganese (III) based oxidative free-radical cyclizations. 2. Polycyclization reactions proceeding through tertiary cations.
TLDR
In this paper, it was shown that oxidation of a monocyclic radical to a cation precedes cyclization to form 3, 4, 7, and 8, respectively.About:
This article is published in Tetrahedron Letters.The article was published on 1987-01-01. It has received 54 citations till now. The article focuses on the topics: Radical cyclization & Bicyclic molecule.read more
Citations
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Book ChapterDOI
Chemical and physical properties of triangular bridged metal complexes
Roderick D. Cannon,Ross P. White +1 more
Journal ArticleDOI
Total synthesis and antiviral activity of indolosesquiterpenoids from the xiamycin and oridamycin families.
Zhanchao Meng,Haixin Yu,Li Li,Wanyin Tao,Hao Chen,Ming Wan,Peng Yang,David J. Edmonds,Jin Zhong,Ang Li +9 more
TL;DR: Evaluation of the antiviral activity of these compounds revealed that xiamycin A is a potent agent against herpes simplex virus–1 (HSV-1) in vitro and the dimeric congener dixiamYcin C has been synthesized for the first time.
References
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Journal ArticleDOI
Free-radical carbon-carbon bond formation in organic synthesis.
TL;DR: Carboncentered radicals can form bonds with electron-rich or electron-deficient alkenes, allenes, and acetylenes, as well as construct hindered carbon-carbon bonds, which contribute to the importance of such reactions in organic synthesis.
Journal ArticleDOI
Free-radical cyclizations
TL;DR: In this article, the main types of reactions which free radicals undergo to generate new carbon-carbon bonds are discussed, including the addition of free radicals to unsaturated bonds and aromatic substitution reactions.