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Journal ArticleDOI

Mass spectra and organic analysis—II

B. Willhalm, +2 more
- 01 Jan 1964 - 
- Vol. 20, Iss: 5, pp 1185-1209
TLDR
The mass spectra of a number of phenyl ethers in which the oxygen atom forms part of a heterocyclic ring have been measured and it is suggested that ions that are stabilized by the operation of the so-called "ortho-effect" are generally cyclic as mentioned in this paper.
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This article is published in Tetrahedron.The article was published on 1964-01-01. It has received 122 citations till now. The article focuses on the topics: Mass spectrum & Fragmentation (mass spectrometry).

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Citations
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Journal ArticleDOI

Massenspektrometrie und IHRE anwendung auf strukturelle und stereochemische probleme—LXVII

TL;DR: In this article, the Zerfallsreaktion organischer Molekule unter Elektronenbeschuss, die formal einer retro-Diels-Alder-Reaktion entspricht, wird diskutiert.
Journal ArticleDOI

Chromatographic analysis of unsaponifiable compounds of olive oils and fat-containing foods.

TL;DR: Several analytical cases of the main classes of components of the unsaponifiable matter obtained from olive oils or food matrices are reported, especially capillary gas chromatography.
Journal ArticleDOI

Alkaloids of Piper longum Linn—I : Structure and synthesis of piperlongumine and piperlonguminine

TL;DR: Piperlongumine and piperlonguminine are shown to be N-(3,4,5-trimethoxycinnamoyl)-Δ5-piperidin-2-one and isobutylamide of piperic acid respectively.
Book ChapterDOI

Some newer aspects of mass spectrometric ortho effects

TL;DR: In this paper, a review of electron impact induced ortho effects is presented, where the most important topics are hydrogen transfer and especially the question of concerted or multistep reaction, the influence of the structure on the selectivity of hydrogen migration via higher-membered transition states, the apparent cleavage of carbon/heteroatom bonds induced by hydrogen transfer, the redox processes which formally correspond to photochemical transformations, but which are completely different according to the reaction mechanisms, the different types of cyclization reactions, and the field of exchange processes preceding or accompanying unimolecular
References
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Journal ArticleDOI

Structures of aplysin and aplysinol, naturally occurring bromo-compounds

TL;DR: The structures of aplysin and aply sinol, new sesquiterpenoid aromatic bromo-compounds isolated from Aplysia kurodai, are elucidated and biogenesis of a plysin, debromoaplysin and a Plysinol is discussed.
Journal ArticleDOI

Mass Spectra of Aromatic Esters

E. M. Emery
- 01 Oct 1960 - 
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