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Journal ArticleDOI

Materials for Solid Oxide Fuel Cells

Allan J. Jacobson
- 09 Feb 2010 - 
- Vol. 22, Iss: 3, pp 660-674
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TLDR
A short review of the types and properties of materials that have been considered for each of these components is presented with an emphasis on the requirements for operation at intermediate temperature (500−800 °C).
Abstract
Solid oxide fuel cells (SOFCs) have the promise to improve energy efficiency and to provide society with a clean energy producing technology. The high temperature of operation (500−1000 °C) enables the solid oxide fuel cell to operate with existing fossil fuels and to be efficiently coupled with turbines to give very high efficiency conversion of fuels to electricity. Solid oxide fuel cells are complex electrochemical devices that contain three basic components, a porous anode, an electrolyte membrane, and a porous cathode. In this short review, a survey of the types and properties of materials that have been considered for each of these components is presented with an emphasis on the requirements for operation at intermediate temperature (500−800 °C). Some directions for future research are discussed.

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Citations
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Readily processed protonic ceramic fuel cells with high performance at low temperatures

TL;DR: A proton-conduction cathode and simpler fabrication enable lower-temperature operation of methane-fueled ceramic fuel cells and develops a proton-, oxygen-ion–, and electron-hole–conducting PCFC-compatible cathode material that greatly improved oxygen reduction reaction kinetics at intermediate to low temperatures.
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Solution Combustion Synthesis of Nanoscale Materials

TL;DR: This Review focuses on the analysis of new approaches and results in the field of solution combustion synthesis (SCS) obtained during recent years, emphasizing the chemical mechanisms that are responsible for rapid self-sustained combustion reactions.
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Recent advances in high temperature electrolysis using solid oxide fuel cells: A review

TL;DR: In this article, solid oxide electrolysis cells (SOEC) have attracted a great interest in the last few years, as they offer significant power and higher efficiencies compared to conventional low temperature electrolysers.
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Nonstoichiometric Oxides as Low-Cost and Highly-Efficient Oxygen Reduction/Evolution Catalysts for Low-Temperature Electrochemical Devices

TL;DR: Reduction/Evolution Catalysts for Low-Temperature Electrochemical Devices Dengjie Chen, ⊥,∇ Chi Chen,†,⊥ Zarah Medina Baiyee,‡,§ and Francesco Ciucci*,†.
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Oxide-ion and proton conducting electrolyte materials for clean energy applications: structural and mechanistic features

TL;DR: This critical review presents an overview of the various classes of oxide materials exhibiting fast oxide-ion or proton conductivity for use as solid electrolytes in clean energy applications such as solid oxide fuel cells.
References
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Journal ArticleDOI

Materials for fuel-cell technologies

TL;DR: Recent progress in the search and development of innovative alternative materials in the development of fuel-cell stack is summarized.
Journal ArticleDOI

A high-performance cathode for the next generation of solid-oxide fuel cells

TL;DR: BSCF is presented as a new cathode material for reduced-temperature SOFC operation and demonstrated that BSCF is ideally suited to ‘single-chamber’ fuel-cell operation, where anode and cathode reactions take place within the same physical chamber.
Journal ArticleDOI

Solid State Ionics

TL;DR: The main feature of this area of science and emerging technology is the rapid transport of atomic or ionic species within solids, and various phenomena, of both scientific and technological interest, that are related to it as discussed by the authors.
Journal ArticleDOI

Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes

TL;DR: These advances have led to dozens of active SOFC development programs in both stationary and mobile power and contributed to commercialization or development in a number of related technologies, including gas sensors, solid-state electrolysis devices, and iontransport membranes for gas separation and partial oxidation.
Journal ArticleDOI

Appraisal of Ce1−yGdyO2−y/2 electrolytes for IT-SOFC operation at 500°C

TL;DR: In this article, the authors evaluated thermodynamic and electrical conductivity data to select the most appropriate electrolyte composition for IT-SOFC operation at 500°C and found that the Gd 3+ ion is the preferred dopant, compared to Sm 3+ and Y 3+, at this temperature.
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