Journal ArticleDOI
Matrix photoionization studies of trifluoromethyl halide systems. Infrared spectra of the CF3+, CF2X+, and CF3X+ cations in solid argon
Reads0
Chats0
About:
This article is published in Journal of the American Chemical Society.The article was published on 1978-03-01. It has received 58 citations till now. The article focuses on the topics: Matrix (mathematics) & Photoionization.read more
Citations
More filters
Journal ArticleDOI
Trifluoromethylation Enables a 3D Interpenetrated Low-Band-Gap Acceptor for Efficient Organic Solar Cells
Hanjian Lai,Hanjian Lai,Qiaoqiao Zhao,Zi-Yi Chen,Hui Chen,Pengjie Chao,Yulin Zhu,Yongwen Lang,Nan Zhen,Daize Mo,Yuan-Zhu Zhang,Feng He +11 more
TL;DR: In this article, a trifluoromethylation was used for non-fullerene acceptors, resulting in an ultra-narrow band-gap molecule named BTIC-CF3-γ.
Journal ArticleDOI
Heats of Formation of Simple Perfluorinated Carbon Compounds
TL;DR: In this paper, the heats of formation of CF3, its cation and anion, CF4, C2F4, and :CFCF3 have been calculated at high levels of ab initio molecular orbital theory.
Journal ArticleDOI
Argon matrix photolysis and photoionization studies of benzene. Absorption spectrum of benzene cation and benzene dimer cation
TL;DR: The 552.5 and 900 nm absorption energy and the difference between the sharp origins for the first two benzene photoelectron bands have been investigated in this paper, and a tentative assignment of the sharp, weak 5 52.5 nm band to the vibronically allowed 2E2g+e2u←2E1g transition of C6H6+ is in accord with deuterium isotopic shifts and predictions from the gas phase fluorescence spectra of fluorine substituted benzene cations.
Journal ArticleDOI
The reaction of F atoms with methane in an argon matrix
TL;DR: In this paper, a microwave discharge through an Ar:CF 4 or Ar:NF 3 sample flowing through an Al 2 O 3 tube provides a suitable source of F atoms for studies of the infrared spectra of the products of their reaction with CH 4 trapped in an argon matrix at 14 K.