Journal ArticleDOI
Measurement and Correlation for the Solubility of Sodium p-Toluenesulfonate, Sodium Sulfite, and Sodium p-Methylphenoxide in Aqueous Sodium Hydroxide Solutions and Sodium Sulfite in Aqueous Ethanol Solutions
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TLDR
In this article, the authors investigated the solubilities of NaPTS, Na2SO3, NaCRS, and NaMethylphenoxide (NaCRS) in aqueous NaOH solutions and Na 2SO3 in aaqueous ethanol solutions.Abstract:
The solubilities of sodium p-toluenesulfonate (NaPTS), sodium sulfite (Na2SO3), and sodium p-methylphenoxide (NaCRS) in aqueous NaOH solutions and Na2SO3 in aqueous ethanol solutions were investigated using a dynamic method over the temperature range from 277 to 341 K at atmospheric pressure. The experimental results showed that the solubilities of NaPTS, Na2SO3, and NaCRS in aqueous NaOH solutions and Na2SO3 in aqueous ethanol solutions decreased distinctly with the solute-free mass fraction of NaOH (w40) and ethanol (w50). Further, there were obvious transition points in the solubility–temperature curves of NaPTS and Na2SO3 in aqueous NaOH solutions, and the transition points shifted to lower temperature as w40 rose. The forming of transition point was due to the different equilibrium solid phase, which was revealed by characterization of the equilibrium solid phase. But the transition points in the solubility–temperature curves of Na2SO3 in aqueous ethanol solutions remained constant at different w50 v...read more
Citations
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Salts and 1‐propanol induced aqueous two‐phase systems: phase separation and application
Chuhan Fu,Shaoqu Xie +1 more
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Thermodynamic Studies of Solubilityfor Naphthalene in 12 Solvents from 279 to 330 K
TL;DR: In this paper, the solubilities of naphthalene in decalin, octane, dodecane, dichloromethane, triethylamine, trichloroethane, o-dichlorobenzene, 1-octanol, 2-octanone, 4-methyl-2-penta...
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Solubility Measurement, Model Correlation, and Solute–Solvent Interactions of Pidotimod in Nine Pure Solvents and Two Binary Solvents at Temperatures Ranging from 278.15 to 323.15 K
TL;DR: The solubility of pidotimod was measured by employing a dynamic equilibrium method in nine pure solvents [water, methanol, benzyl alcohol, ethanol, acetone, iso-propanol, n-butanol, acetonitrile, a....
Journal ArticleDOI
Solubility of 4-Chloro-2,5-dimethoxynitrobenzene, 4-Chloro-2,5-dimethoxyaniline, and 2,5-Dimethoxyaniline in Binary and Pure Solvents: Determination and Modeling
TL;DR: In this article, the authors used the dynamic method over the temperature range of (277 to 340) K at atmosphere pressure, to investigate the solubility of 4-chloro-2,5-dimethoxynitrobenzene (CDMB) and 4- chloro- 2,5dimethoxideyaniline (CDMA) in methanol-water and ethanol-water solvent mixtures, where solute-free mass fraction of methanolis and ethanol range from 0.2 to 0.8.
Journal ArticleDOI
Dual-functional turn-on fluorescent probe for discriminative sulfite and sulfide detection via organic/aqueous ratio tuning and its application in real samples
TL;DR: In this paper , a dual-functional probe for detecting sulfite and sulfide was proposed, which is based on a dimethylaminonaphthalene-oxazaborine fluorophore and a dicyanovinyl reaction site.
References
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