Journal ArticleDOI
Mechanism of the Formation of Di-t-butylnitroxide from t-Nitrobutane and Sodium Metal
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This article is published in Journal of the American Chemical Society.The article was published on 1964-02-01. It has received 93 citations till now. The article focuses on the topics: Sodium.read more
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Electron-Spin Resonance Study of Mainstream and Sidestream Cigarette Smoke: Nature of the Free Radicals in Gas-Phase Smoke and in Cigarette Tar
TL;DR: It is proposed that a steady-state concentration of reactive radicals exists in gas phase cigarette smoke, and it is suggested that this steady state is produced by the slow oxidation of nitric oxide to the more reactive nitrogen dioxide, followed by the reaction of nitrogen dioxide with reactive organic molecules in smoke (such as olefins and dienes).
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The relative participation of liver microsomal amine oxidase and cytochrome P-450 in N-demethylation reactions
TL;DR: Part of the formaldehyde formed from the sec-N-methylamine arises from non-cytochrome P-450-dependent oxidation catalyzed by pig, hamster, and rat liver microsomes, demonstrating that formaldehyde can be inhibited by adding methimazole, a non-formaldehyde-producing substrate specific for the microsomal mixed-function amine oxidase, to the reaction media.
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C-Nitroso compounds—VII
TL;DR: In this article, it was shown that acryl radicals combine with nitroso compounds to give acyl-alkyl-nitroxides, which are identified by their ESR spectra.
Journal ArticleDOI
Nuclear magnetic resonance of organic free radicals
TL;DR: The conditions under which N.M.R. spectra of organic free radicals can be observed are discussed in this paper, where the sign and magnitude of the interaction between the unpaired electron and the nucleus are investigated.
Journal ArticleDOI
Die elektrochemische oxidation aliphatischer nitroxyl-radikale
W. Sümmermann,U. Deffner +1 more
TL;DR: In this paper, the electrochemical oxidation of seven different nitroxyl radicals has been investigated in acetonitrile at a platinum electrode, and the electrostatic solvation enthalpies of two oxammonium ions were calculated.