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Journal ArticleDOI

Mechanisms of Zr(IV) and La (III) catalysis of the reduction of nitrate at mercury

James A. Cox, +1 more
- 01 May 1979 - 
- Vol. 24, Iss: 5, pp 517-520
TLDR
In this article, it was shown that Zr(IV) catalysis of the reduction of nitrate at mercury electrodes occur because of electrostatic interaction of the nitrate with adsorbed Zr (IV), and the overall process is an 8electron reduction to ammonia.
About
This article is published in Electrochimica Acta.The article was published on 1979-05-01. It has received 22 citations till now. The article focuses on the topics: Polarography & Nitrate.

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Citations
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Journal ArticleDOI

Cathodic electrodeposition of oxide semiconductor thin films and their application to dye-sensitized solar cells

TL;DR: In this paper, a three-step process was proposed for the preparation of porous anatase TiO2 thin film modified by cis-dithiocyanato bis(4,4V-dicarboxylic acid-2,2V-bipyridine)ruthenium(II) (N3) dye has been achieved.
Journal ArticleDOI

Mechanism of cathodic electrodeposition of zinc oxide thin films from aqueous zinc nitrate baths

TL;DR: In this article, the authors investigated the mechanism of electrodeposition of zinc oxide (ZnO) thin films from aqueous solution of zinc nitrate by using a rotating disk electrode.
Journal ArticleDOI

Self-Assembly of Zinc Oxide Thin Films Modified with Tetrasulfonated Metallophthalocyanines by One-Step Electrodeposition

TL;DR: In this article, it was found that the adsorption of tetrasulfonated metallophthalocyanines onto the growing surface of ZnO strongly affects the crystal growth and the orientation of the zinc oxide crystallites, creating a film looking like stacking disks aligned perpendicular to the substrate.
Journal ArticleDOI

Electrodeposition of ZnO Nanorod Arrays on Transparent Conducting Substrates–a Review

TL;DR: In this article, a comprehensive review on various electrosynthesis procedures developed to obtain the nanorods of desired structure, diameter, density on the substrate is provided, and the growth mechanisms and influence of different parameters such as the type and concentration of Zn2+ and OH− precursors on the morphology of obtained ZnO films are discussed.
References
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Journal ArticleDOI

Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.

TL;DR: In this paper, the integral equations obtained from the boundary value problems were solved and extensive data were calculated which permit construction of stationary electrode polarograms from theory, making it possible to develop diagnostic criteria so that unknown systems can be characterized by studying the variation of peak current, half-peak potential, or ratio of anodic to cathodic peak currents as a function of rate of voltage scan.
Journal ArticleDOI

The potential-sweep method: A theoretical analysis☆

TL;DR: Potential sweep method for organic and adsorption analyses, showing relation between galvanostatic and fast potential sweep transients, noting mathematical analysis of current-potential transients as mentioned in this paper.
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Stability of some inorganic and organic complex compounds of zirconium and hafnium

TL;DR: In this article, a review of the results of a number of investigations of equilibrium reaction in the complexing of ions of Zt a+ and Hf 4+ with inorganic and organic addends is presented.
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Electrostatic effect of specifically adsorbed electroinactive ions upon electrode processes

TL;DR: In this paper, the average potential at the position occupied by the reacting particle in the transition state was derived from a simple model of the double layer in the presence of specific ionic adsorption.
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