Journal ArticleDOI
Metal atom incorporation studies on the phases with NZP structure: □NbTiP3O12
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TLDR
A wide variety of electropositive elements of the periodic table can be inserted into the vacant sites in the host framework structure of hexagonal NbTiP 3 O 12 (an analog of nasicon) to give rise to isostructural phases as discussed by the authors.About:
This article is published in Journal of Solid State Chemistry.The article was published on 1987-09-01. It has received 38 citations till now. The article focuses on the topics: Isostructural.read more
Citations
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Hydrogen insertion studies in the NASICON type material
TL;DR: In this paper, the reduced product is characterized by powder X-ray diffraction (XRD) and Mossbauer spectroscopy and its unit cell parameters are deduced, which indicates that CaTiFeP3O12 could not be reduced completely.
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Mössbauer spectroscopic investigations of metal incorporation within nasicon-related NbTiP3O12
TL;DR: In this article, the results of the Nasicon-related NbTiP3O12 (Nasicon = Na3Zr2Si2PO12) reaction with elemental iron to give materials of composition FexNbNiTiP 3O12(0.00 < x⩽ 0.33) resulted in the incorporation of Fe2+ in a distribution of similar environments within the type I octahedral interstitial sites.
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Li intercalation studies on AFeMP3O12
TL;DR: Li intercalation in AFeMP3O12 (A=Ca, Sr, Ba; M=Ti, Zr) was achieved using n-BuLi in this paper.
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Magnetic interactions in the compounds Fe0.33NbTiP3O12, Sn0.5NbTiP3O12 and Mn0.5NbTiP3O12
TL;DR: In this paper, the reaction of elemental iron, tin and manganese with the white diamagnetic niobium titanium phosphorus oxide NbTiP3O12 produces blue-black compounds of composition Fe0.33NbTIP3O 12, Sn0.5NbTiTIP 3O12, Mn0.
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Glass reactive sintering as an alternative route for the synthesis of NZP glass–ceramics
Sébastien Chenu,Ronan Lebullenger,Patricia Bénard-Rocherullé,Guillaume Calvez,Olivier Guillou,Jean Rocherullé,Abdessamad Kidari,Mickael J. Pomeroy,Stuart Hampshire +8 more
TL;DR: In this paper, a glass with the appropriate composition in the NaPO3-Sn(II)O-W(VI)O3 ternary diagram is prepared by a conventional melting and casting technique.
References
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Lithium insertion into manganese spinels
TL;DR: In this article, Li has been inserted chemically and electrochemically into Mn3O4 and Li[Mn2]O4 at room temperature from X-ray diffraction.
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The Crystal Structure of NaM2IV(PO4)3; MeIV = Ge, Ti, Zr.
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Topochemical reactions of rutile related structures with lithium
TL;DR: In this paper, the topochemical lithiation of rutile related MO 2 with n-BuLi and in nonaqueous lithium electrochemical cells is reported, which illustrates the importance of electronic conductivity and cell volume to substantial lithium incorporation.
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Lithium incorporation by vanadium pentoxide
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Phase transformation in Na1+xSixZr2P3−xO12 compounds
TL;DR: In this paper, various compositions (x from 1 to 3) were obtained from chemically coprecipitated powders, and the 1.6-approximation was obtained from a single sample.