Journal ArticleDOI
Metal .sigma.-hydrocarbyls, MRn. Stoichiometry, structures, stabilities, and thermal decomposition pathways
Reads0
Chats0
About:
This article is published in Chemical Reviews.The article was published on 1976-04-01. It has received 294 citations till now. The article focuses on the topics: Thermal decomposition.read more
Citations
More filters
Journal ArticleDOI
Preparation, Structure, and Reactivity of Nonstabilized Organoiron Compounds. Implications for Iron-Catalyzed Cross Coupling Reactions
TL;DR: It is shown that nucleophiles unable to undergo beta-hydride elimination, such as MeLi, PhLi, or PhMgBr, rapidly reduce Fe(3+) to Fe(2+) and then exhaustively alkylate the metal center.
Journal ArticleDOI
The metathesis reactions: from a historical perspective to recent developments
TL;DR: The history of metathesis catalysts can be traced back to the work of Yves Chauvin and the discovery of efficient catalysts by R. R. Schrock and R. H. Grubbs.
Journal ArticleDOI
1,n-Dicarbanionic Titanium Intermediates from Monocarbanionic Organometallics and Their Application in Organic Synthesis
Journal ArticleDOI
Chemistry of organosilicon compounds
TL;DR: In this paper, two 1,2-disilacyclobutenes were prepared by the reaction of tetramethyldisilene with acetylenes, and several reactions of these new 1 2 disilacy clobutenets including oxidation, silylene insertion, iron carbonyl insertion, and addition to acetylene and dienes are reported.
Related Papers (5)
.sigma.-Alkyl and -aryl complexes of the group 4-7 transition metals
R. R. Schrock,G. W. Parshall +1 more