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Mineralogy and petrology of Grenada, Lesser Antilles island arc

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The mineralogy and petrology of volcanic and plutonic rocks from the island of Grenada are described in this paper, where the conditions of equilibration of basanitoids with potential upper mantle materials using the results of high pressure experiments are compared with estimates from thermodynamic data.
Abstract
The mineralogy and petrology of volcanic and plutonic rocks from the island of Grenada are described The volcanic rocks include basanitoids, alkalic and subalkalic basalts, andesites and dacites Phenocryst phases in the basanitoids and basalts are olivine (Fo90−71), zoned calcic augite, spinel ranging from ferrian pleonaste through chromite to titaniferous magnetite, and plagioclase Some of the basalts contain pargasitic amphibole Andesites and dacites generally contain hypersthene and augite, and one pigeonite-hypersthene-augite-bearing andesite was found Apatite commonly occurs as a phenocryst in the andesites and dacites and quartz is present in some dacites as well as being a possible xenocryst in both alkalic and subalkalic basalts Plutonic cumulates found as ejected fragments in tuffs and ashes are composed of variable proportions of olivine, magnetite, calcic augite, amphibole and plagioclase One peridotitic (ol-cpx-opx) fragment was found but spinel or garnet peridotitis are absent Despite the alkalic nature of the association, calcalkalic characteristics such as calcic plagioclase, restricted Feenrichment in coexisting pyroxenes and generally low TiO2 content relative to oceanic suites are present in Grenada Estimates of conditions of equilibration of the basanitoids with potential upper mantle materials using the results of high-pressure experiments are compared with estimates from thermodynamic data Equating $$a_{{\text{SiO}}_{\text{2}} } $$ and $$a_{{\text{Al}}_{\text{2}} {\text{O}}_{\text{3}} } $$ basanitoid with hypothetical garnet peridotite assemblages gives a pressure and temperature of equilibration in the region of 35–38 kbar and 1550–1625 ° K Experimental results are not supportive of these estimates

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Citations
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Journal ArticleDOI

High pressure experimental calibration of the olivine-orthopyroxene-spinel oxygen geobarometer: implications for the oxidation state of the upper mantle

TL;DR: In this article, synthetic spinel harzburgite and lherzolite assemblages were equilibrated between 1040 and 1300°C and 0.3 to 2.7 GPa, under controlled oxygen fugacity (fO2).
Journal ArticleDOI

Clinopyroxene composition as a method of identification of the magmatic affinities of paleo-volcanic series

TL;DR: In this article, a set of discrimination diagrams have been derived from a statistical study of the Ti, Cr, Ca, Al and Na contents of over 706 analyses of calcic clinopyroxene phenocrysts from recent volcanic rocks of various magmatic types from various tectonic settings.
Journal ArticleDOI

Sediment subduction and magma genesis in the Lesser Antilles: Isotopic and trace element constraints

TL;DR: In this paper, a suite of volcanic rocks from the Lesser Antilles island arc, including representatives from all the major islands, were analyzed and the Pb, Rb, Cs, Sr, Ba, U, Th, Pb and rare earth elements (REE) were analyzed.
Journal ArticleDOI

Source component mixing in the regions of arc magma generation

TL;DR: A metasomatic addition to the wedge resulting from devolatilization in the slab is the simplest explanation of the marked enrichment of the alkali and alkaline earth elements with respect to the rare earths in island arc basalts, together with the variably developed trends in Pb, Sr and Nd isotopic data toward sedimentary contaminants as mentioned in this paper.
Journal ArticleDOI

The Lesser Antilles volcanic chain : a study in arc magmatism.

TL;DR: In this article, the authors investigated the influence of the sediment component relative to that of hydrous fluids generally increases towards the south of the Lesser Antilles volcanic arc and found that the proportions of each component in the different magma types are still debated, as is the importance of crustal contamination in producing their trace element and isotopic characteristics.
References
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Journal ArticleDOI

The genesis of basaltic magmas

TL;DR: In this paper, the results of a detailed experimental investigation of fractionation of natural basaltic compositions under conditions of high pressure and high temperature were reported, where a single stage, pistoncylinder apparatus has been used in the pressure range up to 27 kb and at temperatures up to 1500° C to study the melting behaviour of several basaltics compositions.
ReportDOI

Thermodynamic properties of minerals and related substances at 298.15 K (25.0 C) and one atmosphere (1.013 bars) pressure and at higher temperatures

TL;DR: A detailed summary of the available thermodynamic data for minerals and related substances in a convenient form for the use of earth scientists can be found in this article, where the authors present a set of tables for high-temperature thermodynamic properties.
Journal ArticleDOI

Melting Relations of Basalt with Equilibrium Water Pressure Less Than Total Pressure

TL;DR: In this paper, a model for the generation of the calcalkaline suite by partial melting of H,O-rich basalts was presented, and the results of the model substantiate the model for partial melting.
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