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Journal ArticleDOI

Modeling phase equilibria of semiclathrate hydrates of CH4, CO2 and N2 in aqueous solution of tetra-n-butyl ammonium bromide

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TLDR
In this paper, the authors proposed a thermodynamic model for gas hydrate system as proposed by Chen and Guo has been extended for semiclathrate hydrates of gases in aqueous solution of TBAB.
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This article is published in Journal of Natural Gas Chemistry.The article was published on 2012-07-01. It has received 62 citations till now. The article focuses on the topics: Hydrate & Clathrate hydrate.

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Journal ArticleDOI

Experimental measurements and thermodynamic modelling of hydrate phase equilibrium conditions for CF4+TBAB aqueous solutions

TL;DR: In this article, CF4 hydrate dissociation conditions in the presence of different TBAB aqueous solutions with the concentrations of 0.05, 0.20, and 0.3 mass fractions were experimentall...
Dissertation

Modelling Phase Equilibria of CO2 Hydrates in Aqueous Solutions of Tetrabutylammonium Bromide

TL;DR: In this paper, a model for phase equilibria of CO2 hydrates in aqueous solutions of tetrabutylammonium bromide (TBAB) has been developed.
OtherDOI

Structures of Noncanonical Clathrates and Related Hydrates

TL;DR: In this article , the structural features of non-canonical clathrate hydrates, including semi-clathrates and ionic clathrates, are discussed, as well as the similarities and structural differences with the canonical amine clathrates of Chapter 5.
References
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Clathrate hydrates of natural gases

TL;DR: In this paper, the authors compared the properties of hydrates and ice with those of natural gas and showed the effect of thermodynamic inhibitors on the formation of hydrate formation and dissolution process.
Journal ArticleDOI

CO2 capture by hydrate crystallization – A potential solution for gas emission of steelmaking industry

TL;DR: In this article, the authors used TBAB as an additive to make the hydrate crystallization condition milder, which made it more suitable for CO2 capture from a gas mixture.
Journal ArticleDOI

A new approach to gas hydrate modelling

TL;DR: In this paper, a two-step hydrate formation mechanism is proposed for gas hydrate, which consists of a quasi-chemical reaction process to form basic hydrate and an adsorption process of smaller gas molecules in the linked cavities of basic hydrates.
Journal ArticleDOI

Phase diagram, latent heat, and specific heat of TBAB semiclathrate hydrate crystals

TL;DR: In this article, the congruent melting points of two types of TBAB hydrates were determined from the phase diagram of semiclathrate hydrate nucleation under the condition of atmospheric pressure, latent and specific heats capacity of TBA-n-butyl ammonium bromide (TBAB) hydrate.
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