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Molybdenum Sulphur Chemistry
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 1 citations till now. The article focuses on the topics: Molybdenum.read more
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Journal ArticleDOI
Synthesis and crystal structure of [PPh4]2[MoS4(CuBr)4]·Me2CO; the assembly of four copper(I) centres about a tetrathiomolybdate(VI) moiety
TL;DR: This paper showed that four edges of the tetrahedral MoS4core are bridged by cuI atoms giving an aggregate of approximate D2d symmetry with µ2-Br bridges linking these aggregates to form a one-dimensional polymeric anion.
Journal ArticleDOI
Synthesis and proton magnetic resonance properties of Fe3Ms4(M = Mo or W) cubane-like cluster dimers
George Christou,C. David Garner +1 more
TL;DR: In this paper, a clear distinction between bridging and terminal ligands is observed and, within each set of bridging, only one resonance is observed for each chemically different proton.
Journal ArticleDOI
Kinetic studies and a molecular orbital interpretation of reactions at bridging sulfur ligands in dimeric molybdenum complexes
Journal ArticleDOI
A novel cubane-type Mo4S4 cluster
TL;DR: In this paper, the authors proposed a method for affinement in the context of ENE, a methylenediaminetetraacetate (EDE) and cristallise dans P2 1 /c avec Z=4.
Journal ArticleDOI
The chemistry of the hydrazido(1–)-ligand. Preparations and crystal structures of [Mo(NHNHCO2Me)(NNCO2Me)(S2CNMe2)2], [Mo(NHNMePh)(NNMePh)(S2CNMe2)2]BPh4, and [ReCl2(NHNHCOPh)(NNHCOPh)(PPh3)2]. Mechanism of formation of substituted hydrazines from [Mo(NNRPh)2(S2CNMe2)2](R = Me or Ph)
Jonathan R. Dilworth,Richard A. Henderson,Phillip L. Dahlstrom,Terrence Nicholson,Jon Zubieta +4 more
TL;DR: In this paper, the preparation of three complexes containing a hydrazido(1)-ligand is described, together with a kinetic study of the intermediacy of such a species in the hydrazine-forming reaction of acid with [Mo(NNRPh)2(S2CNR′2)2]-R = R′= Me; R = Ph, R = Et.