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Molybdenum Sulphur Chemistry
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 1 citations till now. The article focuses on the topics: Molybdenum.read more
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Journal ArticleDOI
Crevice co-ordination: binding of a ligand molecule in a molecular crevice. Crystal and molecular structures of µ-oxo-µ-pyridine-µ-sulphido-bis[(OO′-di-isopropyl phosphorodithioato)oxo-molybdenum(V)] and µ-oxo-µ-pyridazine-µ-sulphido-bis[(OO′-di-isopropyl phosphorodithioato)oxomolybdenum(V)]
TL;DR: In this article, the crystal structures of two 1:1 adducts have been determined and are reported, namely [{Mo(O)(X)2(O(S)(S)(py)](2) and [{M O(X) 2(O)S)(pydz)](3), with cell dimensions a= 17.200(10), b= 12.690(11), c= 15.448(9)A, β= 110.0(2), and Z= 4.93(1)A).
Journal ArticleDOI
Preparation and molecular structure of oxodihalogenobis(dialkyldithiocarbamato)molybdenum(VI) complexes
TL;DR: In this article, the structure of MoOCl2(S2CNEt2) was refined to R 0.040 by using 2 350 independent reflections measured by diffractometer.
Journal ArticleDOI
Synthesis and Crystal Structures of Trinuclear Molybdenum Chloro Sulfido Clusters Coordinated with Triethylphosphine and Methanol
TL;DR: Two triethylphosphine complexes of trinuclear molybdenum chlorosulfido clusters have been synthesized in this paper, and the crystal structures of the complexes can be formulated as [Mo3(μ3-S)(μ-S)3Cl4(PEt3)n(MeOH)5−n]
Journal ArticleDOI
Triply bridged binuclear thiolate complexes of oxomolybdenum(V). Synthesis of [Mo2O2(SR)6Z]- (Z = OR', SR', NR'2) and crystal structures of (Et4N)[Mo2O2(SCH2CH2O)2Cl3], (Et4N)[Mo2O2(SCH2CH2O)3Cl], and (Pr3NH)[Mo2O2(SCH2CH2O)3(SCH2CH2OH)]
Journal ArticleDOI
[Mo4(NO)4(S2)6O]2−, A Novel Highly Symmetric Polynuclear Complex with Two “Handle‐Shaped” and Four “Roof‐Shaped” Coordinated S Bridging Ligands at a Tetragonal Mo4 Disphenoid
TL;DR: The complete manuscript of as mentioned in this paper appears in: Angew. Chem. Suppl. 1982, 1167. DOI:10.1002/anie.198211670].