Journal ArticleDOI
Noble metal catalysis. II. Hydratocarbonylation reaction of olefins with carbon monoxide to give saturated acids
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This article is published in Journal of Organic Chemistry.The article was published on 1973-09-01. It has received 110 citations till now. The article focuses on the topics: Electrochemical reduction of carbon dioxide & Compounds of carbon.read more
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Palladium-catalyzed Reppe carbonylation.
TL;DR: Although hydroesterification yields esters from alkenes, alkynes, and dienes in fewer steps than hydroformylation does, the latter has some advantages at the current state of the art; thus, continued effort in the field is warranted.
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Palladium-Catalyzed Carbonylation Reactions of Alkenes and Alkynes
TL;DR: In this paper, the authors summarize the recent catalyst developments and selected organic applications in this area and present a plethora of palladium catalysts and various synthetic protocols are available for the synthesis of valuable carboxylic acids and acrylic acids as well as their derivatives.
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Palladium‐Catalyzed Oxidative Carbonylation Reactions
TL;DR: The oxidative addition step could be potentially avoided in oxidative reactions, but only few reviews exist in this area, and the recent development in the oxidative carbonylation reactions are summarized.
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Alcoholysis of acylpalladium(II) complexes relevant to the alternating copolymerization of ethene and carbon monoxide and the alkoxycarbonylation of alkenes: the importance of Cis-coordinating phosphines.
Piet W. N. M. van Leeuwen,Martin Alexander Zuideveld,Bert H. G. Swennenhuis,Zoraida Freixa,Paul C. J. Kamer,Kees Goubitz,Jan Fraanje,Martin Lutz,Anthony L. Spek +8 more
TL;DR: It is concluded that ester elimination from acylpalladium complexes with alcohols requires cis geometry of the acyl group and coordinating alcohol.